Synthesis, characterization, and optimum reaction conditions of oligo-3-aminopyridine and its Schiff base oligomer

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dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.contributor.authorKaya, İsmet
dc.contributor.authorGülel, Reyhan
dc.date.accessioned2025-01-27T20:48:02Z
dc.date.available2025-01-27T20:48:02Z
dc.date.issued2005
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe products and the oxidative polycondensation reaction conditions of oligo-3-aminopyridine with H2O2 and NaOCl were studied. In this reaction, NaOCl was observed to be more active than H2O2 and optimum reaction conditions were determined. Oligo-3-aminopyridine (OAP) was synthesized from the oxidative polycondensation of 3-aminopyridine (AP) with NaOCl and H2O2 in an aqueous acidic medium at 25 degrees-90 degrees C. The products were characterized by H-1 NMR, FT-IR, UV-Vis, and elemental analysis. The number-average molecular weight, weight-average molecular weight, and polydispersity index values of OAP synthesized were found to be 250, 800g mol(-1), and 3.20, respectively, using NaOCl, and 240, 840g mol(-1), and 3.50, respectively, using H2O2. The respective values of the Schiff base were 1140, 5190g mol(-1), and 4.55. At optimum reaction conditions, yields of the reaction products were 80.1% (H2O2) and 82.0% (NaOCl). About 90% AP was converted into OAP. TG analyses showed that OAP was stable towards thermo-oxidative decomposition. The weight loss of OAP was found to be 5, 50, and 92 at 125 degrees, 617 degrees, and 1000 degrees C, respectively. The weight loss of oligo-aminopyridinylazomethinephenol (OAPAP) was found to be 5, 50, and 80.50 at 175 degrees, 660 degrees, and 1000 degrees C, respectively. Also, a new oligomeric Schiff base was synthesized from the condensation of OAP with salicylaidehyde and their structures and properties were determined.
dc.identifier.doi10.1080/10236660500356528
dc.identifier.endpage122
dc.identifier.issn1023-666X
dc.identifier.issue1-2
dc.identifier.scopus2-s2.0-29244481661
dc.identifier.scopusqualityQ3
dc.identifier.startpage109
dc.identifier.urihttps://doi.org/10.1080/10236660500356528
dc.identifier.urihttps://hdl.handle.net/20.500.12428/25120
dc.identifier.volume10
dc.identifier.wosWOS:000233909300008
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofInternational Journal of Polymer Analysis and Characterization
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectoligo-3-aminopyridine
dc.subjectoxidative polycondensation
dc.subjectSchiff base
dc.titleSynthesis, characterization, and optimum reaction conditions of oligo-3-aminopyridine and its Schiff base oligomer
dc.typeArticle

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