A new donor-acceptor carbazole derivative: Electrochemical polymerization and photo-induced charge transfer properties

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dc.authoridKoyuncu, Sermet/0000-0001-8352-8326
dc.contributor.authorKoyuncu, Fatma Baycan
dc.contributor.authorKoyuncu, Sermet
dc.contributor.authorOzdemir, Eyup
dc.date.accessioned2025-01-27T20:49:28Z
dc.date.available2025-01-27T20:49:28Z
dc.date.issued2011
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractA new donor-acceptor carbazole derivative containing N-2-(2-ethylhexyl)-1,8-napthalimide as acceptor pendant was synthesized at three steps and directly coated on to ITO glass surface by using electro-chemical process. Subsequently, electrochemical co-polymerization of this monomer was carried out by using 3,4-ethylenedioxythiophene (EDOT) as co-monomer to give electrochromic polymer film. Spectro-electrochemical studies indicated that co-polymer films exhibit relatively lower band gap than that of homo-polymer. Consequently, photo-induced energy and charge transfer properties from the donor-carbazole to naphthalimide-acceptor were studied by using cyclic voltammetry, UV-vis absorption and emission spectroscopy. (C) 2011 Elsevier B.V. All rights reserved.
dc.description.sponsorshipCanakkale Onsekiz Mart University Grants Commission [2009/17]; Scientific and Technical Research Council of Turkey (TUBITAK) [109T516]
dc.description.sponsorshipWe gratefully acknowledge the supports from Canakkale Onsekiz Mart University Grants Commission (Project #: 2009/17) and also grateful to Scientific and Technical Research Council of Turkey (TUBITAK, project #: 109T516) for financial support.
dc.identifier.doi10.1016/j.synthmet.2011.03.008
dc.identifier.endpage1013
dc.identifier.issn0379-6779
dc.identifier.issue11-12
dc.identifier.scopus2-s2.0-79957937419
dc.identifier.scopusqualityQ1
dc.identifier.startpage1005
dc.identifier.urihttps://doi.org/10.1016/j.synthmet.2011.03.008
dc.identifier.urihttps://hdl.handle.net/20.500.12428/25170
dc.identifier.volume161
dc.identifier.wosWOS:000292676600014
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofSynthetic Metals
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectCarbazole
dc.subject1,8-Naphthalimide
dc.subjectDonor-acceptor polymer
dc.subjectElectrochromic polymer
dc.subjectCharge transfer properties
dc.titleA new donor-acceptor carbazole derivative: Electrochemical polymerization and photo-induced charge transfer properties
dc.typeArticle

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