A New Donor-Acceptor Double-Cable Carbazole Polymer with Perylene Bisimide Pendant Group: Synthesis, Electrochemical, and Photovoltaic Properties

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dc.authoridZAFER, CEYLAN/0000-0002-8407-2452
dc.authoridKoyuncu, Sermet/0000-0001-8352-8326
dc.contributor.authorKoyuncu, Sermet
dc.contributor.authorZafer, Ceylan
dc.contributor.authorKoyuncu, Fatma Baycan
dc.contributor.authorAydin, Banu
dc.contributor.authorCan, Mustafa
dc.contributor.authorSefer, Emre
dc.contributor.authorOzdemir, Eyup
dc.date.accessioned2025-01-27T20:51:49Z
dc.date.available2025-01-27T20:51:49Z
dc.date.issued2009
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractWe report here electrochemical synthesis of novel soluble donor-acceptor (D-A) polymer with suitably functionalized perylenetetracarboxylic diimide dye derivative covalently linked to carbazole moiety (Cbz-PDI). The band gap, E, was measured using UV-Vis spectroscopy and compared with that obtained by cyclic voltammetry (CV). Efficient intramolecular electron transfer from carbazole-donor to perynediimide-acceptor leads to remarkable fluorescence quenching of the perylene core. Furthermore, spectroelectrochemical property and surface morphology of the polymer film were investigated. Characteristic monoanion and dianion radical bands on the UV-Vis absorption spectra attributed to the electrochemical reduction of the neutral polymer were observed. During the reduction process, red color of the film turned into blue and violet, respectively. Finally, the photovoltaic performance of the D-A double-cable polymer was checked and nearly 0.1% electrical conversion efficiency is obtained under simulated AM 1.5 solar light with 100 mW/cm(2) radiation power. (C) 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 6280-6291, 2009
dc.description.sponsorshipState Planning Organization of Turkey (DPT); Technical and Scientific Research Council of Turkey (TUBITAK)
dc.description.sponsorshipThe authors gratefully acknowledge the supports from the State Planning Organization of Turkey (DPT) and Technical and Scientific Research Council of Turkey (TUBITAK).
dc.identifier.doi10.1002/pola.23671
dc.identifier.endpage6291
dc.identifier.issn0887-624X
dc.identifier.issue22
dc.identifier.scopus2-s2.0-70350227177
dc.identifier.scopusqualityN/A
dc.identifier.startpage6280
dc.identifier.urihttps://doi.org/10.1002/pola.23671
dc.identifier.urihttps://hdl.handle.net/20.500.12428/25531
dc.identifier.volume47
dc.identifier.wosWOS:000271670000033
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherJohn Wiley & Sons Inc
dc.relation.ispartofJournal of Polymer Science Part A-Polymer Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WoS_20250125
dc.subjectcarbazole
dc.subjectconjugated polymers
dc.subjectdonor-acceptor polymers
dc.subjectelectrochemical polymerization
dc.subjectelectrochemistry
dc.subjectheteroatom-containing polymers
dc.subjectorganic solar cells
dc.subjectperylene
dc.titleA New Donor-Acceptor Double-Cable Carbazole Polymer with Perylene Bisimide Pendant Group: Synthesis, Electrochemical, and Photovoltaic Properties
dc.typeArticle

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