Enzyme Catalyzed Synthesis of Water Soluble Mesalazine Oligomers and Evaluation of their Efficiency in Polypropylene Stabilization

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dc.authorid0000-0002-1377-5580en_US
dc.authorid0000-0002-9813-2962en_US
dc.authorscopusid13405405500en_US
dc.authorscopusid56250747600en_US
dc.authorwosidEPR-7274-2022en_US
dc.authorwosidABD-2324-2020en_US
dc.contributor.authorBilici, Ali
dc.contributor.authorÇoğal, Yunus
dc.contributor.authorGeçibesler, İbrahim Halil
dc.contributor.authorKaya, İsmet
dc.date.accessioned2022-12-05T12:21:05Z
dc.date.available2022-12-05T12:21:05Z
dc.date.issued2021en_US
dc.departmentFakülteler, Fen Fakültesi, Kimya Bölümü
dc.description.abstract5-Aminosalicylic acid, also known as mesalazine, was oxidized via biocatalytic pathway using Horseradish Peroxidase as catalyst. The spectroscopic measurement results indicated that amine and hydroxyl groups in monomer structure participated in polymerization reaction and carboxyl groups did not. The oxidation product consisted of a mixture of branched oligophenol and oligoaniline units and was well soluble in both organic and inorganic solvents including methanol, DMSO and H2O. The photoluminescence studies showed that both 5-aminosaliyclic acid and oxidation product exhibited green and blue light emission, respectively. Both compounds were subject to antioxidant assays. The oxidation product exhibited moderate antioxidant ability for all three assays. However, 5-aminosalicylic acid failed to chelate the ferrous ions. As antioxidant stabilizer for polypropylene, the efficiency of the oxidation product was also investigated.en_US
dc.identifier.citationAli Bilici, Çogal, Y., Geçibesler, İ. H., & İsmet, Kaya (2021). Enzyme Catalyzed Synthesis of Water Soluble Mesalazine Oligomers and Evaluation of their Efficiency in Polypropylene Stabilization. Polymer Science, Series B, 63(6), 710–721. https://doi.org/10.1134/s1560090421060051en_US
dc.identifier.doi10.1134/S1560090421060051
dc.identifier.endpage721en_US
dc.identifier.issn1560-0904
dc.identifier.issn1555-6123
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-85124349677
dc.identifier.startpage710en_US
dc.identifier.urihttps://doi.org/10.1134/S1560090421060051
dc.identifier.urihttps://hdl.handle.net/20.500.12428/3755
dc.identifier.volume63en_US
dc.identifier.wosWOS:000750844700006
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorBilici, Ali
dc.institutionauthorKaya, İsmet
dc.language.isoen
dc.publisherSpringeren_US
dc.relation.ispartofPolymer Science, Series B. Polymer Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAntioxidanten_US
dc.subjectOxidationen_US
dc.subjectPolymerizationen_US
dc.subjectPolyethyleneen_US
dc.subjectDerivativesen_US
dc.subjectAciden_US
dc.titleEnzyme Catalyzed Synthesis of Water Soluble Mesalazine Oligomers and Evaluation of their Efficiency in Polypropylene Stabilization
dc.typeArticle

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