Synthesis And Characterization Of Novel 1,2,3-Triazole-Bridged Oxime Polyurethanes Obtained From An Isomannide Derivative
| dc.authorid | 0000-0003-4965-8754 | en_US |
| dc.authorscopusid | 25230307000 | en_US |
| dc.authorwosid | J-6910-2012 | en_US |
| dc.contributor.author | Bayrak, Fatih | |
| dc.contributor.author | Oral, Ayhan | |
| dc.contributor.author | Ay, Kadir | |
| dc.date.accessioned | 2023-07-24T11:59:57Z | |
| dc.date.available | 2023-07-24T11:59:57Z | |
| dc.date.issued | 2021 | en_US |
| dc.department | Fakülteler, Fen Fakültesi, Kimya Bölümü | |
| dc.description.abstract | Polyurethanes (PUs) are synthesized by the reaction of diisocyanates and diols and are widely used in furniture foams, thermal insulation, coatings, and adhesives. In this work, a 1,2,3-triazole-bridged dioxime (compound 6) as a diol source was synthesized from isomannide via tosylation, azidation, and cyclization-addition and used in the syntheses of new PUs. A new carbohydrate-based linear P-1 was syn-thesized by the reaction of 6 and 1,6-hexamethylene diisocyanate (1,6-HMDI). Besides, three new linear PUs (P-2, P-3, and P-4) were synthesized by the reaction of 6, isomannide compound (used in different molar ratios), and 1,6-HMDI. The thermal properties of the new PUs were determined by thermogravime-try (TG), their molecular structures were characterized by FTIR, 1H- and 13C-NMR, and the molecular weights of some polymers were determined by GPC/SEC. Additionally, the surface characteristics of the synthesized PUs were examined via scanning electron microscopy (SEM). | en_US |
| dc.identifier.citation | Bayrak, F., Oral, A., & Ay, K. (2021). Synthesis and characterization of novel 1,2,3-triazole-bridged oxime polyurethanes obtained from an isomannide derivative. Macedonian Journal of Chemistry and Chemical Engineering, 40(1), 75-87. doi:10.20450/MJCCE.2021.2220 | en_US |
| dc.identifier.doi | 10.20450/MJCCE.2021.2220 | |
| dc.identifier.endpage | 87 | en_US |
| dc.identifier.issn | 1857-5552 | |
| dc.identifier.issn | 1857-5625 | |
| dc.identifier.issue | 1 | en_US |
| dc.identifier.scopus | 2-s2.0-85109129671 | |
| dc.identifier.startpage | 75 | en_US |
| dc.identifier.uri | https://doi.org/10.20450/MJCCE.2021.2220 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12428/4427 | |
| dc.identifier.volume | 40 | en_US |
| dc.identifier.wos | WOS:000681515600009 | |
| dc.identifier.wosquality | Q4 | |
| dc.indekslendigikaynak | Web of Science | |
| dc.indekslendigikaynak | Scopus | |
| dc.institutionauthor | Oral, Ayhan | |
| dc.language.iso | en | |
| dc.publisher | Macedonian Journal of Chemistry and Chemical Engineering | en_US |
| dc.relation.ispartof | Macedonian Journal of Chemistry and Chemical Engineering | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.rights | Attribution-NonCommercial 3.0 United States | * |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc/3.0/us/ | * |
| dc.subject | 1,2,3-triazole | en_US |
| dc.subject | 1,6-hexamethylene diisocyanate | en_US |
| dc.subject | Azide | en_US |
| dc.subject | Dioxime | en_US |
| dc.subject | Isomannide | en_US |
| dc.subject | Poly(oxime-urethane) | en_US |
| dc.subject | Polyurethane | en_US |
| dc.title | Synthesis And Characterization Of Novel 1,2,3-Triazole-Bridged Oxime Polyurethanes Obtained From An Isomannide Derivative | |
| dc.type | Article |
