Synthesis, Spectral Studies, Antimicrobial Activity and Crystal Structures of Phosphaza-Lariat Ethers

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dc.authoridDulger, Basaran/0000-0002-3184-2652
dc.authoridOzay, Hava/0000-0002-4184-7801
dc.authoridUnver, Huseyin/0000-0003-3968-4385
dc.contributor.authorOzay, Hava
dc.contributor.authorYıldız, Mustafa
dc.contributor.authorUnver, Huseyin
dc.contributor.authorDulger, Basaran
dc.date.accessioned2025-01-27T20:50:31Z
dc.date.available2025-01-27T20:50:31Z
dc.date.issued2011
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractPhosphaza-lariat ethers, which are known as 2,2-[4,4'-(2,2'-oxybis(ethane-2,1-diyl)bis(oxy))dianilino]-4,4,6,6-tetrachlorocyclo-2 lambda(5),4 lambda(5),6 lambda(5-)triphosphazatriene(spiro) (1), 2,2-[4,4'-(2,2'-(ethane-1,2-diylbis(oxy))bis(ethane-2,1-diyl))bis(oxy)dianilino]-4,4,6,6-tetrachlorocyclo-2 lambda(5),4 lambda(5),6 lambda(5)-triphosphazatriene(spiro) (2) and 2,2-[4,4'-(2,2'-(ethane-1,2-diylbis(oxy))bis(ethane-2,1-diyl))bis(oxy)dianilino]-4,4-bis(tertbutylamino)-6,6-dichlorocyclo-2 lambda(5),4 lambda(5),6 lambda(5)-triphosphazatriene (3) have been synthesized. The structures of the compounds (1, 2 and 3) are characterized by elemental analysis, IR, H-1, C-13, P-31 NMR and mass spectroscopic techniques. The antimicrobial activities of the compounds have been screened in vitro against the organisms. The structures of the compounds 1, 2 and 3 have also been examined by means of cyrstallographically. The compounds 1, 2 and 3 crystallize in the orthorhombic space group Pbca, hexagonal space group P4(3)2(1)2 and tetragonal space group P4(2)/n, respectively. They have unit cell parameters: a = 15.607(1), 10.6723(2) and 26.0308(9), b = 15.667(2), 10.6723(2) and 26.0308(9), c = 19.481(3), 23.3633(6) and 10.6033(4) angstrom, V = 4763.4(1), 2661.03(1) and 7184.8(4) angstrom(3), D-x = 1.570, 3.031 and 1.258 g cm(-3) and Z = 8, 8 and 8, respectively.
dc.description.sponsorshipScientific and Technical Research Council of Turkey (TUBITAK) [109T565]
dc.description.sponsorshipThe authors are greatful to the Scientific and Technical Research Council of Turkey (TUBITAK) for the financial support of this work, grant number 109T565.
dc.identifier.endpage2436
dc.identifier.issn0970-7077
dc.identifier.issn0975-427X
dc.identifier.issue6
dc.identifier.scopus2-s2.0-79955525868
dc.identifier.scopusqualityQ4
dc.identifier.startpage2430
dc.identifier.urihttps://hdl.handle.net/20.500.12428/25513
dc.identifier.volume23
dc.identifier.wosWOS:000293193000018
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherAsian Journal Of Chemistry
dc.relation.ispartofAsian Journal of Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectPhosphazene
dc.subjectSpectroscopic studies
dc.subjectAntimicrobial activities
dc.subjectCrystal structure
dc.subjectSpiro
dc.titleSynthesis, Spectral Studies, Antimicrobial Activity and Crystal Structures of Phosphaza-Lariat Ethers
dc.typeArticle

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