Preparation and Characterization of Sepiolite-Poly(ethyl methacrylate) and Poly(2-hydroxyethyl methacrylate) Nanocomposites

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dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.contributor.authorBenlikaya, Ruhan
dc.contributor.authorAlkan, Mahir
dc.contributor.authorKaya, İsmet
dc.date.accessioned2025-01-27T21:01:51Z
dc.date.available2025-01-27T21:01:51Z
dc.date.issued2009
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractPoly(ethyl methacrylate) (PEMA) and poly(2-hydroxyethyl methacrylate) (PHEMA) nanocomposites with sepiolite in pristine and silylated form were prepared using the solution intercalation method and characterized by the measurements of XRD, TEM, FTIR-ATR, TG/DTG, and DSC. The TEM analysis indicated that the volume fraction of fibers in sepiolite decreased and the fiber bundles dispersed in PEMA and PHEMA at a nanometer scale. These results regarding TEM micrographs were in agreement with the data obtained by XRD. The increase in thermal stability of nanocomposites of PEMA is higher than that of PHEMA according to the data obtained from TG curves. The DTG analysis revealed that sepiolite/modified sepiolite caused some changes, as confirmed by FTIR in the thermal degradation mechanism of the polymers. T(g) temperatures of PEMA and PHEMA usually increased upon the addition of sepiolite/modified sepiolite. In addition, modification of sepiolite with 3-APTS had a slight influence on thermal properties of the nanocomposites. POLYM. COMPOS., 30:1585-1594, 2009. (c) 2008 Society of Plastics Engineers
dc.description.sponsorshipBalikesir University [2006/01]; TUBITAK [106T453]
dc.description.sponsorshipContract grant sponsor: TUBITAK; contract grant number: 106T453. DO1 10.1002/pc.20731
dc.identifier.doi10.1002/pc.20731
dc.identifier.endpage1594
dc.identifier.issn0272-8397
dc.identifier.issue11
dc.identifier.scopus2-s2.0-70350217514
dc.identifier.scopusqualityQ1
dc.identifier.startpage1585
dc.identifier.urihttps://doi.org/10.1002/pc.20731
dc.identifier.urihttps://hdl.handle.net/20.500.12428/27212
dc.identifier.volume30
dc.identifier.wosWOS:000271222200006
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherJohn Wiley & Sons Inc
dc.relation.ispartofPolymer Composites
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectThermal-Degradation
dc.subjectPoly(Ethyl Methacrylate)
dc.subjectSepiolite
dc.subjectAdsorption
dc.subjectComposites
dc.subjectReinforcement
dc.subjectDecomposition
dc.subjectAcrylate)
dc.subjectBehavior
dc.subjectSilica
dc.titlePreparation and Characterization of Sepiolite-Poly(ethyl methacrylate) and Poly(2-hydroxyethyl methacrylate) Nanocomposites
dc.typeArticle

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