Biosynthesis and Characterization of Organosoluble Conjugated Poly(2-aminofluorene) with the Pyrazine Bridged

Basit Öğe Kaydı
dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.contributor.authorBilici, Ali
dc.contributor.authorKaya, İsmet
dc.contributor.authorYıldırım, Mehmet
dc.date.accessioned2025-01-27T20:14:10Z
dc.date.available2025-01-27T20:14:10Z
dc.date.issued2010
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this paper, the results on horseradish peroxidase (HRP)-catalyzed oxidative polymerization of amine-functionalized fluorene monomer, 2-amino fluorene (AV). are reported. The-resulting polymer exhibits an exciting molecular structure and spectral properties. FT-IR and NMR studies show that the two fluorene units come together by forming an intermediate six-membered pyrazine ring and these formed dimeric units are linked to the each other through C-C couplings to produce fully conjugated polymer structure (AFP). Further characterizations were performed by means of GPC, TGA, DSC, SEM, CV (cyclic voltammetry), fluorescence analyses, and solubilly tests. Optical band gaps of this electroactive polymer was found to be 2.6.0 eV. AFP emits red light and its emission maxima is drastically affected by the kind of the solvents used. 10 addition, obtained polymer is soluble in common polar and apolar organic solvents.
dc.identifier.doi10.1021/bm1005382
dc.identifier.endpage2601
dc.identifier.issn1525-7797
dc.identifier.issn1526-4602
dc.identifier.issue10
dc.identifier.pmid20815396
dc.identifier.scopus2-s2.0-77957871897
dc.identifier.scopusqualityQ1
dc.identifier.startpage2593
dc.identifier.urihttps://doi.org/10.1021/bm1005382
dc.identifier.urihttps://hdl.handle.net/20.500.12428/20969
dc.identifier.volume11
dc.identifier.wosWOS:000282840200008
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherAmer Chemical Soc
dc.relation.ispartofBiomacromolecules
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectAnodic-Oxidation
dc.subjectConducting Poly(9-Alkylfluorene)
dc.subjectPolyfluorene Derivatives
dc.subjectEnzymatic-Synthesis
dc.subjectFluorene
dc.subjectPolymers
dc.subject2-Aminofluorene
dc.subjectPolymerization
dc.subjectCopolymers
dc.subjectPoly(9,9-Dialkylfluorene)
dc.titleBiosynthesis and Characterization of Organosoluble Conjugated Poly(2-aminofluorene) with the Pyrazine Bridged
dc.typeArticle

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