Facile synthesis and characterization of trimesic acid-Cu based metal organic frameworks

Basit Öğe Kaydı
dc.authoridŞahiner, Nurettin / 0000-0003-0120-530X
dc.authoridDemirci, Şahin / 0000-0001-7083-1481
dc.authoridSel, Kıvanç / 0000-0002-4623-5206
dc.authoridÖztürk, Ömer Faruk / 0000-0002-9244-6805
dc.contributor.authorŞahiner, Nurettin
dc.contributor.authorSel, Kıvanç
dc.contributor.authorÖztürk, Ömer Faruk
dc.contributor.authorDemirci, Şahin
dc.contributor.authorTerzi, Gözde
dc.date.accessioned2025-01-27T21:00:09Z
dc.date.available2025-01-27T21:00:09Z
dc.date.issued2014
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractMetal-organic frameworks based on trimesic acid (TMA) as organic linker and Cu (II) as metal ions from different metal salts such as CuCl2, Cu(NO3)(2), CuSO4 and Cu(CH3COOH)(2) were prepared in relatively environmentally friendly media e.g., at room temperature in DI water and at the boiling point of ethanol. The prepared TMA-Cu MOFs showed very interesting porosity and optical coloring based on the source of the used metal salts and preparation medium. The prepared MOFs were characterized in terms of their porosity with BET measurements and it was found that about 850 m(2)/g for the MOF prepared from Cu(NO3)(2) salt in ethanol. The amounts of metal ions connected to TMA were determined by atomic absorption spectroscopy measurements (AAS) after dissolution of TMA-Cu MOFs by concentrated HCl treatments. From MS measurements the mole ratio of Cu(II) to TMA was found to vary between 1.5 and 2, depending on the source of metal ions and the solvent used during preparation. The structural analysis and thermal characterization of the prepared MOFs were done by using FT-IR and TGA analysis, respectively. Additionally, TMA-Cu based MOF disks were prepared and their conductivities were determined by I V measurements. The conductivity of TMA-Cu MOFs was calculated to be between 8.26E-08 and 5.29E-11 S/cm. (C) 2014 Elsevier B.V. All rights reserved.
dc.description.sponsorshipScientific and Technological Research Council of Turkey [110T649]
dc.description.sponsorshipThis work is supported by the Scientific and Technological Research Council of Turkey (110T649).
dc.identifier.doi10.1016/j.apsusc.2014.07.023
dc.identifier.endpage669
dc.identifier.issn0169-4332
dc.identifier.issn1873-5584
dc.identifier.scopus2-s2.0-84906713596
dc.identifier.scopusqualityQ1
dc.identifier.startpage663
dc.identifier.urihttps://doi.org/10.1016/j.apsusc.2014.07.023
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26950
dc.identifier.volume314
dc.identifier.wosWOS:000341464100093
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofApplied Surface Science
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectTMS-Cu metal-organic frameworks
dc.subjectMOFs
dc.subjectPorous materials
dc.subjectConductive MOFs
dc.titleFacile synthesis and characterization of trimesic acid-Cu based metal organic frameworks
dc.typeArticle

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
[ X ]
İsim:
Nurettin Sahiner_Makale.pdf
Boyut:
1.48 MB
Biçim:
Adobe Portable Document Format
İndir

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Fizik Bölümü Koleksiyonu
Kimya Bölümü Koleksiyonu
Nanobilim ve Teknoloji Araştırma ve Uygulama Merkezi Yayın Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu