Synthesis and characterization of cage structured flame resistant melamine and pentaerythritol based polymer networks

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dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.authoridKaraer Yağmur, Hatice / 0000-0002-3728-1825
dc.contributor.authorKaya, İsmet
dc.contributor.authorİriş, Ruhsar Ela
dc.contributor.authorKaraer Yağmur, Hatice
dc.date.accessioned2025-01-27T20:44:15Z
dc.date.available2025-01-27T20:44:15Z
dc.date.issued2023
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this study, a Schiff base 2,4,6-tris(4-hidroksibenzimino)-1,3,5-triazine (HT) was synthesized from condensation reaction of 4-hydroxybenzaldehyde and melamine. Subsequently, various imine or ether bond cage polymers were synthesized using 2,4,6-tris(4-hydroxybenzimino)-1,3,5-triazine (HT), pentaerythritol (PT), 1,5-dibromopentane (DP), and p-xylylene dibromide (DX) in DMF. The structures of the compounds were characterized using FT-IR, 1H, 13C-NMR and TGA measurements. The surface morphologies, particle ratious and the glass transition temperatures of polymers were found from SEM, DLS and DSC measurements, respectively. The melamine-based polymers PHTDX and PHTDP were synthesized from the monomer HT. Pentaerythritol-based PPTDX and PPTDP polymers were synthesized from the monomer PT. Melamine (M) and pentaerythritol are used in many applications, such as fire-resistant coatings and flame-retardant plastics. Thermally stable polymers were prepared with melamine and pentaerythritol. Based on SEM images, the polymers were found to have a porous structure. These pores make the polymers flame retardant by trapping combustible gases during thermal degradation. The limiting oxygen index values of PHTDX, PHTDP, PPTDX, and PPTDP at 1000 & DEG;C were reported to be 43.96, 40.42, 31.35 and 23.11, respectively, in TGA measurements.Graphical AbstractSynthesis and characterization of cage structured flame resistant melamine and pentaerythritol based polymer networksIsmet Kaya, Ruhsar Ela Iris, Hatice Karaer YagmurGraphical AbstractSynthesis and characterization of cage structured flame resistant melamine and pentaerythritol based polymer networksIsmet Kaya, Ruhsar Ela Iris, Hatice Karaer Yagmur
dc.description.sponsorshipCanakkale Onsekiz Mart University scientific research project commission [FYL-2018-2596]
dc.description.sponsorshipThe authors thank Canakkale Onsekiz Mart University scientific research project commission for support with the project number (Project Nu.: FYL-2018-2596).
dc.identifier.doi10.1007/s10965-023-03761-z
dc.identifier.issn1022-9760
dc.identifier.issn1572-8935
dc.identifier.issue10
dc.identifier.scopus2-s2.0-85171629692
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1007/s10965-023-03761-z
dc.identifier.urihttps://hdl.handle.net/20.500.12428/24519
dc.identifier.volume30
dc.identifier.wosWOS:001073500300001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Polymer Research
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectCage structured polymers
dc.subjectMelamine-based Schiff base
dc.subjectPentaerythritol
dc.subjectThermal degradation
dc.titleSynthesis and characterization of cage structured flame resistant melamine and pentaerythritol based polymer networks
dc.typeArticle

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