Synthesis, spectral properties, and antimicrobial activity of 2-arylamino,-2,4,4,6,6-pentachloro-1,3,5,2?5,4?5, 6?5-triazatriphosphines and poly[bis(4-fluorophenylamino)phosphazene]

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dc.contributor.authorYildiz, M.
dc.contributor.authorYilmaz, S.
dc.contributor.authorDolger, B.
dc.date.accessioned2025-01-27T20:50:30Z
dc.date.available2025-01-27T20:50:30Z
dc.date.issued2007
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstract2-(4-Chloro and 4-fluorophenylamino)-2,4,4,6,6-pentachloro-1,3,5,2 lambda(5),4 lambda(5),6 lambda(5)-triazatriphosphinines and poly [bis(4-fluoropwhenylamino)phosphazene] were synthesized by reactions of 4-fluoroaniline and 4-chloroaniline with 2,2,4,4,6,6-hexachloro-1,3,5,2 lambda(5),4 lambda(5),6 lambda(5)-triazatriphosphinine and poly(dichlorophosphazene), respectively, in tetrahydrofuran under argon at -20 degrees C, followed by heating under reflux. The products were isolated by column chromatography and were characterized by FTIR, NMR (H-1, C-13, P-31), and mass spectra, termogravimetry, and high-performance liquid chromatography. Antimicrobial activity of the monomeric compounds and polymer against 9 bacteria and 5 yeast cultures was evaluated by the disk diffusion method in dimethyl sulfoxide relative to a number of commercial antibiotics and antifungal agents. Aminophosphazene derivatives exhibited a broad spectrum of activity against both Gram-positive and Gram-negative bacterial with a magnitude comparable to reference antimicrobial agents. The polymeric product turned out to be more potent than the monomeric compounds.
dc.identifier.doi10.1134/S1070363207120079
dc.identifier.endpage2122
dc.identifier.issn1070-3632
dc.identifier.issue12
dc.identifier.scopus2-s2.0-38849117174
dc.identifier.scopusqualityQ3
dc.identifier.startpage2117
dc.identifier.urihttps://doi.org/10.1134/S1070363207120079
dc.identifier.urihttps://hdl.handle.net/20.500.12428/25510
dc.identifier.volume77
dc.identifier.wosWOS:000252852500007
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherMaik Nauka/Interperiodica/Springer
dc.relation.ispartofRussian Journal of General Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectPhosphorus-Nitrogen Compounds
dc.subjectCyclophosphazenes
dc.subjectPolyphosphazenes
dc.subjectHexachlorocyclotriphosphazatriene
dc.subjectProducts
dc.subjectPolymer
dc.titleSynthesis, spectral properties, and antimicrobial activity of 2-arylamino,-2,4,4,6,6-pentachloro-1,3,5,2?5,4?5, 6?5-triazatriphosphines and poly[bis(4-fluorophenylamino)phosphazene]
dc.typeArticle

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