Synthesis and characterizations of poly(ether)/poly(phenol)s including azomethine coupled benzothiazole side chains: the effect of reaction conditions on the structure, optical, electrochemical, electrical and thermal properties

dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.authoridYıldırım, Mehmet / 0000-0001-9948-9106
dc.contributor.authorYıldırım, Mehmet
dc.contributor.authorKaya, İsmet
dc.date.accessioned2025-01-27T20:56:22Z
dc.date.available2025-01-27T20:56:22Z
dc.date.issued2014
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractA new Schiff base, 4-((6-ethoxybenzothiazole-2-ylimino)methyl)benzene-1,2-diol (3,4-HBAEBT) was synthesized by the condensation reaction of 3,4-dihydroxybenzaldehyde (3,4-HBA) and 2-amino-6-ethoxybenzothiazole. The Schiff base, then, was converted to its polymer derivatives by oxidative polycondensation reaction in both organic (P-1) and aqueous alkaline medium (P-2). Spectral observations indicated different structural properties for each polymerization condition. Organic and aqueous alkaline medium produced poly(ether) and poly(phenol) structures, respectively. The obtained polymers were separately studied with respect to optical, electrochemical, electrical and thermal properties. With exception of thermal degradation behaviors, the other investigated properties as well as morphological characteristics of both polymers were considerably different. In the fluorescence measurements a solvatochromic effect was recorded and the emission colors of the polymers could be changed as turquoise-green by solvent change.
dc.identifier.doi10.1007/s00289-014-1238-7
dc.identifier.endpage3084
dc.identifier.issn0170-0839
dc.identifier.issn1436-2449
dc.identifier.issue12
dc.identifier.scopus2-s2.0-85027948681
dc.identifier.scopusqualityQ1
dc.identifier.startpage3067
dc.identifier.urihttps://doi.org/10.1007/s00289-014-1238-7
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26386
dc.identifier.volume71
dc.identifier.wosWOS:000345147100002
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofPolymer Bulletin
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectThiazole polymers
dc.subjectPoly(ether)
dc.subjectPoly(phenol)
dc.subjectPolyazomethines
dc.subjectFluorescence
dc.subjectScanning electron microscopy
dc.titleSynthesis and characterizations of poly(ether)/poly(phenol)s including azomethine coupled benzothiazole side chains: the effect of reaction conditions on the structure, optical, electrochemical, electrical and thermal properties
dc.typeArticle

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