Mechanical properties of polypropylene (PP) plus high-density polyethylene (HDPE) binary blends: Non-isothermal degradation kinetics of PP+HDPE (80/20) Blends

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dc.authoridCANLI, Murat/0000-0002-5275-861X
dc.contributor.authorSirin, Kamil
dc.contributor.authorDogan, Fatih
dc.contributor.authorCanli, Murat
dc.contributor.authorYavuz, Mesut
dc.date.accessioned2025-01-27T20:29:33Z
dc.date.available2025-01-27T20:29:33Z
dc.date.issued2013
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this study, the mechanical properties and non-isothermal degradation kinetics of polypropylene (PP), high-density polyethylene (HDPE) with dilauroyl peroxide and their blends in different mixture ratios were investigated. The effects of adding dilauroyl peroxide (0-0.20 wt%) on the mechanical and thermal properties of PP + HDPE blends have been studied. On the other hand, the kinetics of the thermal degradation and thermal oxidative degradation of PP + HDPE (80/ 20 wt%) blends were studied in different atmospheres, to analyze their thermal stability. The kinetic and thermodynamic parameters such as the activation energy, Ea, the pre-exponential factor, A, the reaction order, n, the entropy change, the enthalpy change, and the free energies of activated complex related to PP, HDPE, and blend systems were calculated by means of the several methods on the basis of the single heating rate. A computer program was developed for automatically processing the data to estimate the reaction parameters by using different models. Most appropriate method was determined for each decomposition step according to the least-squares linear regression. Copyright (c) 2013 John Wiley & Sons, Ltd.
dc.identifier.doi10.1002/pat.3135
dc.identifier.endpage722
dc.identifier.issn1042-7147
dc.identifier.issue8
dc.identifier.scopus2-s2.0-84880917075
dc.identifier.scopusqualityQ2
dc.identifier.startpage715
dc.identifier.urihttps://doi.org/10.1002/pat.3135
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22978
dc.identifier.volume24
dc.identifier.wosWOS:000322221200003
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley-Blackwell
dc.relation.ispartofPolymers For Advanced Technologies
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectpolymer blends
dc.subjectthermogravimetry
dc.subjectkinetics
dc.subjectmechanical properties
dc.subjectpolypropylene
dc.subjecthigh-density polyethylene
dc.titleMechanical properties of polypropylene (PP) plus high-density polyethylene (HDPE) binary blends: Non-isothermal degradation kinetics of PP+HDPE (80/20) Blends
dc.typeArticle

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