Toluene vapor sensing characteristics of novel copper(II), indium(III), mono-lutetium(III) and tin(IV) phthalocyanines substituted with 2,6-dimethoxyphenoxy bioactive moieties

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dc.authoridodabas, zafer/0000-0002-0647-0404
dc.authoridPiskin, Mehmet/0000-0002-4572-4905
dc.contributor.authorPiskin, Mehmet
dc.contributor.authorCan, Nursel
dc.contributor.authorOdabas, Zafer
dc.contributor.authorAltindal, Ahmet
dc.date.accessioned2025-01-27T20:41:22Z
dc.date.available2025-01-27T20:41:22Z
dc.date.issued2018
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThis study presents the synthesis, characterization and toluene sensing properties of copper(II), indium(III) acetate, mono-lutetium(III) acetate and tin(IV) phthalocyanines substituted with 2,6-dimethoxyphenol bioactive groups at the peripheral and non-peripheral positions. The effects of the substituent's position on the toluene vapor detection capabilities of these compounds were investigated. Adsorption data were analyzed by using first-order and Elovich equations in order to investigate the adsorption kinetics. It was found that the kinetics of the toluene adsorption strongly depends on the position of the substituent groups. Our results showed that the Elovich equation fits the experimental data well for non-peripherally substituted Pc based sensors, while the pseudo first-order model best describes the adsorption data for peripheral substituted Pc based sensors.
dc.description.sponsorshipFoundation of Marmara University; Commission of Scientific Research (BAPKO) [FEN-C-YLP-140115-0010, FEN-C-YLP-111115-0515]
dc.description.sponsorshipWe are thankful to the Foundation of Marmara University and the Commission of Scientific Research (BAPKO) (Project Nos: FEN-C-YLP-140115-0010 and FEN-C-YLP-111115-0515).
dc.identifier.doi10.1142/S1088424617500900
dc.identifier.endpage197
dc.identifier.issn1088-4246
dc.identifier.issn1099-1409
dc.identifier.issue1-3
dc.identifier.scopus2-s2.0-85042749889
dc.identifier.scopusqualityQ3
dc.identifier.startpage189
dc.identifier.urihttps://doi.org/10.1142/S1088424617500900
dc.identifier.urihttps://hdl.handle.net/20.500.12428/24119
dc.identifier.volume22
dc.identifier.wosWOS:000427932100021
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWorld Sci Publ Co Inc
dc.relation.ispartofJournal of Porphyrins and Phthalocyanines
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectadsorption kinetics
dc.subjectElovich model
dc.subject2,6-dimethoxyphenoxy
dc.subjectphthalocyanine
dc.subjectsynthesis
dc.subjecttoluene sensing
dc.titleToluene vapor sensing characteristics of novel copper(II), indium(III), mono-lutetium(III) and tin(IV) phthalocyanines substituted with 2,6-dimethoxyphenoxy bioactive moieties
dc.typeArticle

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