Electrocatalytic oxidation of hydrazine on poly(4-aminobenzene sulfonic acid)-modified glassy carbon electrode

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dc.authoridSELVI, BEDRETTIN/0000-0002-5819-4894
dc.authoridSaglikoglu, Gulsen/0000-0002-3407-9787
dc.contributor.authorSadikoglu, M.
dc.contributor.authorYilmaz, S.
dc.contributor.authorKurt, I.
dc.contributor.authorSelvi, B.
dc.contributor.authorSari, H.
dc.contributor.authorErduran, N.
dc.contributor.authorUsta, E.
dc.date.accessioned2025-01-27T21:05:27Z
dc.date.available2025-01-27T21:05:27Z
dc.date.issued2016
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractElectrocatalytic oxidation of hydrazine (HZ) was studied on an stable modified glassy carbon electrode (GCE) based on poly (4-aminobenzene sulfonic acid) (4-ABSA) film. The 4-ABSA-modified glassy carbon electrode was prepared by electrochemical polymerization technique in phosphate buffer solution (PBS) (pH 7.0) and its electrochemical behavior were studied by cyclic voltammetry (CV). The polymer filmmodified electrode has very high catalytic ability for electrooxidation of HZ, which appeared as a reduced overpotential in a wide operational pH range of 5-10. Limit of detection (LOD) and limit of quantification (LOQ) were obtained as 1.31 x 10(-7) and 4.35 x 10(-7) M for CV; 7.89 x 10(-8) and 2.63 x 10(-7) M for CA, respectively. The results of experiments showed that prepared modified electrode have good stability, sensitivity and reproducibility for at least one month if stored dry in air.
dc.description.sponsorshipGaziosmanpasa University [2009/33]
dc.description.sponsorshipThis work was supported by Gaziosmanpasa University Scientific Research Fund with a Grant number 2009/33. Authors also thank Assoc. Prof. Dr. Mustafa YILDIZ (Department of Chemistry, Faculty of Arts & Sciences, Canakkale Onsekiz Mart University, Canakkale, Turkey) for scientific discussions on mechanisms of electropolymerization and oxidation of hydrazine.
dc.identifier.doi10.1134/S1023193516060112
dc.identifier.endpage545
dc.identifier.issn1023-1935
dc.identifier.issn1608-3342
dc.identifier.issue6
dc.identifier.scopus2-s2.0-84983036457
dc.identifier.scopusqualityQ4
dc.identifier.startpage539
dc.identifier.urihttps://doi.org/10.1134/S1023193516060112
dc.identifier.urihttps://hdl.handle.net/20.500.12428/27654
dc.identifier.volume52
dc.identifier.wosWOS:000379176300004
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPleiades Publishing Inc
dc.relation.ispartofRussian Journal of Electrochemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subject4-aminobenzene sulfonic acid
dc.subjectmodified-glassy carbon electrode
dc.subjectelectropolymerization
dc.subjectelectrocatalytic-oxidation
dc.subjecthydrazine
dc.subjectvoltammetry
dc.titleElectrocatalytic oxidation of hydrazine on poly(4-aminobenzene sulfonic acid)-modified glassy carbon electrode
dc.typeArticle

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