Synthesis and Characterization of Ruthenium(II) Complexes Bearing Benzimidazole Ligands: For Transfer Hydrogenation Catalysis

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dc.authoriddayan, osman/0000-0002-0764-1965
dc.contributor.authorDayan, Osman
dc.contributor.authorInan, Mustafa Yunus
dc.date.accessioned2025-01-27T20:14:40Z
dc.date.available2025-01-27T20:14:40Z
dc.date.issued2015
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractRu(H) complexes with the general formula [RuCl2(p-cymene)(L1-3)], K1-3, (L1-3: monodentate benzimidazole ligands), [RuCl2(L5-6)(S)], K4-7, (L5-6: tridentate benzimidazole ligands, S: Solvents [methanol or acetonitrile]), and [RuCl2(L5)(L1-2)], K8-9, were synthesized from [RuCl2(p-cymenel dimer and mono- and tridentate benzimidazole ligands. The compounds were characterized by elemental analysis, IR, UV-Vis, and NMR. The synthesized Ru(II) complexes (K1-9) were tested as catalysts for the transfer hydrogenation (TH) of acetophenone to secondary alcohols in the presence of KOH using 2-propanol as a hydrogen source at 82 degrees C. All complexes were active catalysts for TH of acetophenone with good yields under mild conditions (after 60 minutes, yields of up to 97%).
dc.identifier.doi10.1080/15533174.2013.862655
dc.identifier.endpage1024
dc.identifier.issn1553-3174
dc.identifier.issn1553-3182
dc.identifier.issue7
dc.identifier.scopus2-s2.0-84924345600
dc.identifier.scopusqualityN/A
dc.identifier.startpage1018
dc.identifier.urihttps://doi.org/10.1080/15533174.2013.862655
dc.identifier.urihttps://hdl.handle.net/20.500.12428/21169
dc.identifier.volume45
dc.identifier.wosWOS:000351414500015
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Inc
dc.relation.ispartofSynthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectRu(II) complexes
dc.subjecttransfer hydrogenation
dc.subjectbenzimidazoles
dc.subjectacetophenone
dc.titleSynthesis and Characterization of Ruthenium(II) Complexes Bearing Benzimidazole Ligands: For Transfer Hydrogenation Catalysis
dc.typeArticle

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