Comparative study on oxidative and enzyme catalyzed oxidative polymerization of aminophenol compound containing dihalogen
Yükleniyor...
Dosyalar
Tarih
2021
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Properties of polymers were obtained by enzyme catalyzed oxidative polymerization varies according to oxidative polymerization products and thus polymeric materials with diferent properties are obtained. In this study, polymerization of 4-amino2,6-dichlorophenol (ADCP), an aminophenol compound containing dihalogen, was carried out by two diferent methods
and the two methods were compared with each other. One of the methods was oxidative polymerization in the presence of
hydrogen peroxide with heating, and the other was enzyme-catalyzed oxidative polymerization that took place at room temperature in the presence of Horse Radish Peroxidase (HRP) enzyme and hydrogen peroxide. The structural characterization
of the products obtained as a result of oxidative polymerization (PADCP-O) and as a result of enzyme catalyzed oxidative
polymerization (PADCP-E) was performed by 1
H-NMR, 13C-NMR, FT-IR, UV–Vis spectroscopy methods. The molecular
masses of PADCP-O and PADCP-E were analyzed by GPC and the average molecular mass of PADCP-E was found to be
higher than that of PADCP-O. Thermal properties were examined by TGA and it was determined that the thermal stability
of the obtained polymers was higher than that of the monomer. Electrochemical and optical properties were determined by
CV and UV–Vis spectroscopy methods, respectively. Electrochemical and optical band gap values were calculated as 1.61
and 1.33 eV, and 1.88 and 1.83 eV for PADCP-O and PADCP-E, respectively. In addition, it was observed that PADCP-O
emitted green in UV light, while PADCP-E emitted red in DMSO. Surface properties and morphology of polymers were
analyzed by SEM and it was observed that PADCP-O obtained by oxidative polymerization had a spongy structure, but the
enzymatic polymerization product PADCP-E had a uniformly dispersed nanoparticle structure.
Açıklama
Anahtar Kelimeler
Enzymatic Polymerization, Oxidative Polycondensation, 4-Amino-2,6-Dichlorophenol, Nanosphere, HRP
Kaynak
Journal of Polymer Research
WoS Q Değeri
Q2
Scopus Q Değeri
Cilt
28
Sayı
10
Künye
İsmet, Kaya, & Yeldir, E. K. (2021). Comparative study on oxidative and enzyme catalyzed oxidative polymerization of aminophenol compound containing dihalogen. Journal of Polymer Research, 28(10). https://doi.org/10.1007/s10965-021-02733-5
