Synthesis, characterization, and kinetic study of functional polystyrenes

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dc.authoridKaya, Ismet/0000-0002-9813-2962
dc.authoriddayan, osman/0000-0002-0764-1965
dc.contributor.authorDoğan, Fatih
dc.contributor.authorKaya, İsmet
dc.contributor.authorDayan, Osman
dc.contributor.authorOzdemir, Eyuep
dc.date.accessioned2025-01-27T20:43:50Z
dc.date.available2025-01-27T20:43:50Z
dc.date.issued2007
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this study, functionalization of polystyrene (PS) (M,, = 2.5 X 105) was carry out with maleic anhydride in the presence of boron trifluoride dietyhletherade (BF3 OEt2) as catalyst and then functional PS was subjected to condensation reaction with phenyl hydrazine. The structures of both of them were determined by using FTIR, H-1-NMR, elemental analysis, thermogravimetric analysis (TGA) and differential thermal analysis (DTA) techniques. Some physical properties of these two products were investigated and the kinetic parameters of solid state decomposition reactions were determined from TGA curves. The intrinsic viscosity [eta] values of modified PS and condensation products (cPs) found to be 1.024 and 0.7036 dL g(-1) respectively. According to TGA, the weight losses of modified PS and cPs were found to be 84.03 and 81.86%, respectively, at 500 degrees C. (c) 2007 Wiley Periodicals, Inc.
dc.identifier.doi10.1002/app.26837
dc.identifier.endpage3460
dc.identifier.issn0021-8995
dc.identifier.issue5
dc.identifier.scopus2-s2.0-35948970181
dc.identifier.scopusqualityQ2
dc.identifier.startpage3454
dc.identifier.urihttps://doi.org/10.1002/app.26837
dc.identifier.urihttps://hdl.handle.net/20.500.12428/24390
dc.identifier.volume106
dc.identifier.wosWOS:000250410500077
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherJohn Wiley & Sons Inc
dc.relation.ispartofJournal of Applied Polymer Science
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WoS_20250125
dc.subjectpolystyrene
dc.subjectfunctionalization
dc.subjectphysical properties
dc.subjectthermal analysis
dc.titleSynthesis, characterization, and kinetic study of functional polystyrenes
dc.typeArticle

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