Emissive Conjugated Polymer Networks with Tunable Band-Gaps via Thiol-Ene Click Chemistry

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dc.authoridCarter, Kenneth/0000-0002-7081-2296
dc.contributor.authorKoyuncu, Fatma Baycan
dc.contributor.authorDavis, Andrew R.
dc.contributor.authorCarter, Kenneth R.
dc.date.accessioned2025-01-27T20:27:28Z
dc.date.available2025-01-27T20:27:28Z
dc.date.issued2012
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractA series of cross-linked thin films were prepared via thiol-ene click chemistry from 4-phenylethenyl end-capped tunable band gap conjugated polymers with different photoemission. We demonstrate that the emissive color of PLED devices can be successfully tuned from blue to orange via the use of networks prepared using the thiol-ene click reaction. Electrochemical and optical properties were studied by using cyclic voltammetry, UV-vis absorption, and fluorescence spectroscopy, respectively. PLEDs with configuration of ITO/PEDOT:PSS/x-polymer/Ca:Al were fabricated. The devices had turn-on voltages below 8 V and exhibited multicolor emission. Multi layer devices that demonstrated effective color separation and improved color characteristics compared to blended devices were also prepared.
dc.description.sponsorshipNational Science Foundation [DMR-0906695]; Panasonic Boston Laboratory; Scientific and Technical Research Council of Turkey (TUBITAK) [2219]; Direct For Mathematical & Physical Scien; Division Of Materials Research [0906695] Funding Source: National Science Foundation
dc.description.sponsorshipThe authors thank the National Science Foundation (DMR-0906695) and Panasonic Boston Laboratory for support. We also gratefully acknowledge the support from Scientific and Technical Research Council of Turkey (TUBITAK) for 2219-International Postdoctoral Research Scholarship Programme.
dc.identifier.doi10.1021/cm302790a
dc.identifier.endpage4416
dc.identifier.issn0897-4756
dc.identifier.issn1520-5002
dc.identifier.issue22
dc.identifier.scopus2-s2.0-84870195817
dc.identifier.scopusqualityQ1
dc.identifier.startpage4410
dc.identifier.urihttps://doi.org/10.1021/cm302790a
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22698
dc.identifier.volume24
dc.identifier.wosWOS:000313769300019
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherAmer Chemical Soc
dc.relation.ispartofChemistry of Materials
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectthiol-ene click chemistry
dc.subjectpolymeric light-emitting devices
dc.subjecttunable band gap polymers
dc.titleEmissive Conjugated Polymer Networks with Tunable Band-Gaps via Thiol-Ene Click Chemistry
dc.typeArticle

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