Synthesis, characterization and investigation of the photophysical and photochemical properties of highly soluble novel metal-free, zinc(II), and indium(III) phthalocyanines substituted with 2,3,6-trimethylphenoxy moieties

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dc.authoridGurel, Ekrem/0000-0001-6262-2866
dc.authoridodabas, zafer/0000-0002-0647-0404
dc.authoridPiskin, Mehmet/0000-0002-4572-4905
dc.contributor.authorGurel, Ekrem
dc.contributor.authorPiskin, Mehmet
dc.contributor.authorAltun, Selcuk
dc.contributor.authorOdabas, Zafer
dc.contributor.authorDurmus, Mahmut
dc.date.accessioned2025-01-27T20:58:04Z
dc.date.available2025-01-27T20:58:04Z
dc.date.issued2015
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThis work presents the synthesis and characterization of metal-free, zinc((II)), and indium((III)) acetate phthalo-cyanines substituted with 2,3,6-trimethylphenoxy groups at the peripheral and non-peripheral positions. The photophysical (fluorescence quantum yields and lifetimes) and photochemical (singlet oxygen generation and photodegradation under light irradiation) properties of these novel phthalocyanines and un-substituted zinc((II)) and indium((III)) acetate phthalocyanines were investigated in dimethylformamide solution. The effects of the types of substituents and their positions and the variety of central metal ions on the phthalocyanine core on their spectroscopic, photophysical and photochemical properties were also determined. The studied 2,3,6-trimethylphenoxy substituted metal-free, zinc((II)) and indium((III)) acetate phthalocyanines especially indium((III)) acetate derivatives exhibited appropriate photophysical and photochemical properties such as high singlet oxygen generation and these phthalocyanines can be potential Type II photosensitizers for photodynamic therapy in cancer applications.
dc.description.sponsorshipMarmara University; Commission of Scientific Research Projects (BAPKO) [FEN-CYLP-041213-0459, FEN-A-130511-0159]
dc.description.sponsorshipWe are thankful to Marmara University, The Commission of Scientific Research Projects (BAPKO) (project no: FEN-CYLP-041213-0459 and FEN-A-130511-0159).
dc.identifier.doi10.1039/c5dt00304k
dc.identifier.endpage6211
dc.identifier.issn1477-9226
dc.identifier.issn1477-9234
dc.identifier.issue13
dc.identifier.pmid25736967
dc.identifier.scopus2-s2.0-84925324769
dc.identifier.scopusqualityQ2
dc.identifier.startpage6202
dc.identifier.urihttps://doi.org/10.1039/c5dt00304k
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26599
dc.identifier.volume44
dc.identifier.wosWOS:000351476600032
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherRoyal Soc Chemistry
dc.relation.ispartofDalton Transactions
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectSilicon Phthalocyanines
dc.subjectElectronic Absorption
dc.subjectDerivatives
dc.subjectBehavior
dc.subjectPhenoxy
dc.subjectTetra
dc.titleSynthesis, characterization and investigation of the photophysical and photochemical properties of highly soluble novel metal-free, zinc(II), and indium(III) phthalocyanines substituted with 2,3,6-trimethylphenoxy moieties
dc.typeArticle

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