Optical and Electrochemical Properties of PB-ZnO and PB-ZnO/MWCNT Nanocomposite Films Deposited by Chemical Bath

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dc.contributor.authorOzutok, Fatma
dc.contributor.authorYakar, Emin
dc.date.accessioned2025-01-27T20:53:53Z
dc.date.available2025-01-27T20:53:53Z
dc.date.issued2018
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe first aim of this study was to investigate the ZnO modification effect on the prussian blue (PB) films. A second aim of the study was to determine the decoration effect of multi walled carbon nanotube (MWCNT) on the PB-ZnO nanocomposite films which could be deposited by chemical bath. The electrochemical behaviour of PB films was systematically studied using ZnO-orZnO/MWCNT modification. Additionally, detailed optical properties of nanocomposite films were determined by UV-VIS, FTIR and Raman spectroscopy. Optical transparency was severely decreased by ZnO modification onto PB film but the decoration of MWCNTs did not change the optical transparency of film compared to PB film. PB, ZnO and MWCNT presence in the nanocomposite films were proven by FTIR spectrum. Stretching vibration peak of C=N shifted to short-wavelength for PB-ZnO nanocomposite films and same peak disappeared with MWCNT coating due to the structural distortion. ZnO modification and MWCNT coating affected the electrochemical properties due to the different factors such as OH-group effect in film growth process, Zn2+ substitution with Fe2+ site and interaction between ferricyanide ions and oxygen.
dc.identifier.doi10.14447/jnmes.v21i2.462
dc.identifier.endpage126
dc.identifier.issn1480-2422
dc.identifier.issn2292-1168
dc.identifier.issue2
dc.identifier.scopus2-s2.0-85046729943
dc.identifier.scopusqualityQ3
dc.identifier.startpage119
dc.identifier.urihttps://doi.org/10.14447/jnmes.v21i2.462
dc.identifier.urihttps://hdl.handle.net/20.500.12428/25886
dc.identifier.volume21
dc.identifier.wosWOS:000435499300009
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherInt Information & Engineering Technology Assoc
dc.relation.ispartofJournal of New Materials For Electrochemical Systems
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectPrussian blue films
dc.subjectZnO structure
dc.subjectmulti-walled carbon nanotubes
dc.subjectoptical properties
dc.subjectelectrochemical properties
dc.subjectchemical bath deposition
dc.titleOptical and Electrochemical Properties of PB-ZnO and PB-ZnO/MWCNT Nanocomposite Films Deposited by Chemical Bath
dc.typeArticle

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