Metallo-porphyrazines with eight [5-thiopentyl 3,4,5-tris(benzyloxy)benzoate] groups: Synthesis, characterization, aggregation, and solubility behavior

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dc.contributor.authorGonca, Ergun
dc.date.accessioned2025-01-27T20:59:51Z
dc.date.available2025-01-27T20:59:51Z
dc.date.issued2017
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractMetal-free and metallo-porphyrazines having eight 5-hydroxypentylthio units at the peripheral positions have been prepared from 2,3-bis(5-hydroxypentylthio)maleonitrile. By the esterification reaction of magnesium hydroxy-porphyrazine with 3,4,5-tris(benzyloxy)benzoic acid in dicyclohexylcarbodiimide and toluene-p-sulfonic acid, the reactivity of the hydroxypentyl units was indicated. On the other hand, iron porphyrazine derivatives with eight [5-thiopentyl 3,4,5-tris(benzyloxy)benzoate] groups attached to the periphery positions were synthesized. By the reaction of metal-free porphyrazine with iron (II) acetate and further processing with HCl solution, FePzCl was obtained. Finally, by reacting FePzCl with pyridine or pyrazine, [FePz(py)(2)] and [FePz(pyz)](n) complexes were prepared, respectively. The characterizations of target complexes were carried out by utilizing different spectroscopic methods such as FT-IR, UV-vis, mass, H-1 NMR, and C-13 NMR together with elemental analysis. (C) 2016 Elsevier B.V. All rights reserved.
dc.description.sponsorshipScientific Research Fund of Canakkale Onsekiz Mart University [FBA-2014-238]
dc.description.sponsorshipThis work was supported by the Scientific Research Fund of Canakkale Onsekiz Mart University under the Project No. FBA-2014-238.
dc.identifier.doi10.1016/j.molstruc.2016.09.073
dc.identifier.endpage18
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-84991517695
dc.identifier.scopusqualityQ1
dc.identifier.startpage10
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2016.09.073
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26856
dc.identifier.volume1130
dc.identifier.wosWOS:000390731800002
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectPorphyrazine
dc.subject3,4,5-Tris(benzyloxy)benzoic acid
dc.subjectEsterification
dc.subjectMonomeric complex
dc.subjectOligomeric complex
dc.titleMetallo-porphyrazines with eight [5-thiopentyl 3,4,5-tris(benzyloxy)benzoate] groups: Synthesis, characterization, aggregation, and solubility behavior
dc.typeArticle

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