Fly ash as catalyst support material in the hydrolysis of ethylenediamine bisborane for hydrogen production: The use of coal-fired power plant waste

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dc.authoridÖzay, Özgür/0000-0001-6589-9844
dc.authoridOnder, Alper/0000-0002-0775-0053
dc.contributor.authorOnder, Alper
dc.contributor.authorÖzay, Özgür
dc.date.accessioned2025-01-27T20:35:16Z
dc.date.available2025-01-27T20:35:16Z
dc.date.issued2020
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractEfficient, low-cost and safe new systems are still needed for the storage and usage of hydrogen energy, which is considered the most important energy source of the future. For this reason, the aim of this study was to prepare Co-0, Ni-0, and Cu-0 composite catalysts with fly ash (FA) formed by combustion of coal in thermal power plants to be used for the dehydrogenation of ethylenediamine bisborane (EDAB) as a hydrogen source. In the hydrolysis reactions of EDAB, parameters such as metal type, catalyst concentration, temperature, and EDAB concentration were investigated. The FA-Cu-0 composite catalyst was determined to be an effective catalyst system for hydrogen production by hydrolysis of EDAB from among the FA-M-0 composite catalysts. Besides, FA can be used as an effective support material in order to prevent agglomeration of metal particles. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
dc.description.sponsorshipCanakkale Onsekiz Mart University [COMU FLY-2016-714]; Scientific and Technological Research Council of Turkey (BIDEB 2210-C program)
dc.description.sponsorshipThis work was supported by Canakkale Onsekiz Mart University [COMU FLY-2016-714]. This study also includes a part of Alper Onder's master's thesis. Alper Onder is also grateful for support by the Scientific and Technological Research Council of Turkey (BIDEB 2210-C program). The authors would like to thank ICDAS Steel Energy Shipyard and Transportation Industry Inc. for fly ash samples and XRF measurements. We thank Canakkale Onsekiz Mart University Science and Technology Application and Research Center (COBILTUM) and Middle East Technical University Central Laboratory (METU) for all spectral analyses.
dc.identifier.doi10.1016/j.ijhydene.2020.02.093
dc.identifier.endpage11661
dc.identifier.issn0360-3199
dc.identifier.issn1879-3487
dc.identifier.issue20
dc.identifier.scopus2-s2.0-85081218345
dc.identifier.scopusqualityQ1
dc.identifier.startpage11651
dc.identifier.urihttps://doi.org/10.1016/j.ijhydene.2020.02.093
dc.identifier.urihttps://hdl.handle.net/20.500.12428/23614
dc.identifier.volume45
dc.identifier.wosWOS:000524128500024
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofInternational Journal of Hydrogen Energy
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectHydrogen production
dc.subjectEthylenediamine bisborane
dc.subjectCatalytic hydrolysis
dc.subjectCatalyst
dc.subjectFly ash
dc.titleFly ash as catalyst support material in the hydrolysis of ethylenediamine bisborane for hydrogen production: The use of coal-fired power plant waste
dc.typeArticle

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