(Acetonitrile){2,6-bis[1-(2,4,6-trimethylphenylimino)ethyl]pyridine} dichloridoruthenium(II) dichloromethane solvate

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dc.authoridOzdemir, Namik/0000-0003-3371-9874
dc.authoriddayan, osman/0000-0002-0764-1965
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.contributor.authorOzdemir, Namik
dc.contributor.authorDincer, Muharrem
dc.contributor.authorDayan, Osman
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2025-01-27T20:29:17Z
dc.date.available2025-01-27T20:29:17Z
dc.date.issued2007
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn the title compound, [RuCl2(C2H3N)(C27H31N3)] center dot CH2Cl2, the Ru-II ion is six-coordinated in a distorted octahedral arrangement, with the two Cl atoms located in the apical positions, and the pyridine (py) N atom, the two imino N atoms and the acetonitrile N atom located in the basal plane. The two equatorial Ru - N-imino distances are almost equal ( mean 2.087 angstrom) and are substantially longer than the equatorial Ru - N-py bond [1.921 ( 4) angstrom]. It is observed that the N-imino-M-N-py angle for the five-membered chelate rings of pyridine-2,6-diimine complexes is inversely related to the magnitude of the M-N-py bond. The title structure is stabilized by intra- and intermolecular C-H center dot center dot center dot Cl hydrogen bonds, as well as by van der Waals interactions.
dc.identifier.doi10.1107/S0108270107036669
dc.identifier.endpageM409
dc.identifier.issn2053-2296
dc.identifier.pmid17762109
dc.identifier.scopus2-s2.0-34548295513
dc.identifier.scopusqualityN/A
dc.identifier.startpageM407
dc.identifier.urihttps://doi.org/10.1107/S0108270107036669
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22895
dc.identifier.volume63
dc.identifier.wosWOS:000249151500011
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherInt Union Crystallography
dc.relation.ispartofActa Crystallographica Section C-Structural Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectEthylene Polymerization
dc.subjectRuthenium(Ii) Complexes
dc.subjectCatalytic-Activity
dc.subjectCrystal-Structures
dc.subjectCobalt Catalysts
dc.subjectLigands
dc.subjectIron
dc.subjectCyclopropanation
dc.subjectOlefins
dc.subjectChain
dc.title(Acetonitrile){2,6-bis[1-(2,4,6-trimethylphenylimino)ethyl]pyridine} dichloridoruthenium(II) dichloromethane solvate
dc.typeArticle

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