Nickel (II) complex [NiCl2(DMF)2L2] bearing diaminobenzene and sulfonamide: Crystal structure and catalytic application in the reduction of nitrobenzenes

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dc.authoriddayan, serkan/0000-0003-4171-7297
dc.authoridKAYACI, Nilgun/0000-0002-7988-8668
dc.authoridOzdemir, Namik/0000-0003-3371-9874
dc.contributor.authorDayan, Serkan
dc.contributor.authorKayaci, Nilgun
dc.contributor.authorDayan, Osman
dc.contributor.authorOzdemir, Namik
dc.contributor.authorOzpozan, Nilgun Kalaycioglu
dc.date.accessioned2025-01-27T21:03:39Z
dc.date.available2025-01-27T21:03:39Z
dc.date.issued2020
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractA new Bis[N-(2-aminophenyl)benzenesulfonamidej-di-chloro-Bis[O'-N,N-dimethyl-formamide]-nickel (II) complex [NiCl2(DMF)(2)L2] was synthesized in DMF solution in reflux media with NiCl2.2H(2)O and the pre-prepared N-(2-aminophenyl)benzenesulfonamide and the [NiCl2(DMF)(2)L-2] complex was crystallized in DMF/diethyl ether solution, for its single crystal. The complex characterized by FT-IR, elemental analysis, TG-DTA and UV Vis spectrophotometry methods, and its single crystal study were also performed by X-ray spectroscopy. Additionally, the catalytic efficiency of the fabricated [NiCl2(DMF)(2)L-2] complex was determined by UV Vis spectrophotometry in the reduction reaction of 2-nitroaniline (2-NA), 4-nitroaniline (4-NA) and nitrobenzene (NB) in presence of NaBH4 in water. The best conversion obtained as a result of the reduction of nitroarenes in the short time of 10 min. was 62.5 %, which was obtained at the 2-NA reduction. The conversion obtained from of the reduction of nitroarenes, are sequenced as 2-NA (62.5 %) > NB (56.5 %) > 4-NA (25.5%) in 10 min. In addition, the reaction products, both aqueous and short-term, are harmless to the environment, which will provide a significant reaction variety in terms of green chemistry. (C) 2019 Elsevier Ltd. All rights reserved.
dc.identifier.doi10.1016/j.poly.2019.114181
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-85075469588
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1016/j.poly.2019.114181
dc.identifier.urihttps://hdl.handle.net/20.500.12428/27384
dc.identifier.volume175
dc.identifier.wosWOS:000504781100028
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofPolyhedron
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectNickel complex
dc.subjectNitrobenzenes
dc.subjectReduction
dc.subjectCrystal structure
dc.subjectHydrogenation
dc.titleNickel (II) complex [NiCl2(DMF)2L2] bearing diaminobenzene and sulfonamide: Crystal structure and catalytic application in the reduction of nitrobenzenes
dc.typeArticle

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