Tautomeric properties and crystal structure of N-[2-hydroxy-1-naphthylidene]2,5-dichloroaniline

Basit Öğe Kaydı
dc.authoridUnver, Huseyin/0000-0003-3968-4385
dc.contributor.authorYildiz, M.
dc.contributor.authorUnver, H.
dc.contributor.authorErdener, D.
dc.contributor.authorOcak, N.
dc.contributor.authorErdonmez, A.
dc.contributor.authorDurlu, T. Nuri
dc.date.accessioned2025-01-27T20:56:22Z
dc.date.available2025-01-27T20:56:22Z
dc.date.issued2006
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe title compound has been synthesised by the reaction of 2-hydroxy-1-naphthaldehyde with 2,5-dichloroaniline. The compound was characterized by elemental analysis, IR and UV-Visible techniques. The UV-Visible spectra of the Schiff base with OH group in ortho position to the imino group was studied in polar and nonpolar solvents in acidic and basic media. The structure of compound has been examined cyrstallographically. It crystallizes in the or-thorhombic space group P2(1)2(1)2(1) with a = 6.059(1), b = 12.105(2) c = 20.006(2) angstrom, V = 1467.4(3) angstrom(3), D-x = 1.431 g.cm(-3) and Z = 4. The crystal structure was solved by direct methods and refined by full-matrix least squares. Molecule of the title compound N-[2-hydroxy-1-naphthylidene]2,5-dichloroaniline is nearly planar. The molecule contains a strong intramolecular N...H-O hydrogen bond between the imine and hydroxyl group [O1 and N1 = 2.540(4) angstrom]. (c) 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
dc.identifier.doi10.1002/crat.200510632
dc.identifier.endpage606
dc.identifier.issn0232-1300
dc.identifier.issn1521-4079
dc.identifier.issue6
dc.identifier.scopus2-s2.0-33745663100
dc.identifier.scopusqualityQ3
dc.identifier.startpage600
dc.identifier.urihttps://doi.org/10.1002/crat.200510632
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26382
dc.identifier.volume41
dc.identifier.wosWOS:000238682900012
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley-V C H Verlag Gmbh
dc.relation.ispartofCrystal Research and Technology
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectcrystal structure
dc.subjecttautomerism
dc.subjectspectroscopic studies
dc.subjectUV-visible
dc.subjectFT-IR
dc.titleTautomeric properties and crystal structure of N-[2-hydroxy-1-naphthylidene]2,5-dichloroaniline
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu