Synthesis, Crystal Structure and Cyclic Voltammetric Behavior of N-aroyl-N?-(4?-cyanophenyl)thioureas

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dc.authoridARSLAN, N. Burcu/0000-0002-1880-1047
dc.contributor.authorAydin, Fatma
dc.contributor.authorArslan, N. Burcu
dc.date.accessioned2025-01-27T20:16:36Z
dc.date.available2025-01-27T20:16:36Z
dc.date.issued2022
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractHerein, two title compounds, N-benzoyl-N'-(4'-cyanophenyl)thiourea (1) and N-(4-nitrobenzoyl)-N'-(4'-cyanophenyl)thiourea (2) were synthesized in a high yield, via different applications of aroyl isocyanate and 4-aminobenzonitrile. The structure of the prepared compounds was characterized by elemental analysis and FT-IR, H-1, and C-13-NMR spectroscopic methods. The crystal structure of the title compound 1 was determined by an X-ray single-crystal technique and an intramolecular C=O center dot center dot center dot H-N hydrogen bond and intermolecular C=S center dot center dot center dot H-N and C=S center dot center dot center dot H-C hydrogen interactions, which were observed for the crystal structure. The molecular electrostatic potential (MEP) and the Mulliken atomic charges of title compounds 1 and 2 were theoretically calculated and interpreted. Cyclic voltammetric (CV) experiments for the compounds were performed with the glassy carbon electrode. The reduction in potential values of the different functional groups such as nitro and cyano in title compounds were investigated using CV curves.
dc.description.sponsorshipCanakkale Onsekiz Mart University Grants Commission [FYL-2018-2583]
dc.description.sponsorshipThis work was financially supported by the Canakkale Onsekiz Mart University Grants Commission for a research grant (Project Number: FYL-2018-2583).
dc.identifier.doi10.3390/M1316
dc.identifier.issn1422-8599
dc.identifier.issue1
dc.identifier.scopus2-s2.0-85123070391
dc.identifier.scopusqualityQ4
dc.identifier.urihttps://doi.org/10.3390/M1316
dc.identifier.urihttps://hdl.handle.net/20.500.12428/21315
dc.identifier.volume2022
dc.identifier.wosWOS:000774121600001
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherMdpi
dc.relation.ispartofMolbank
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WoS_20250125
dc.subjectN-aroylthioureas
dc.subjectCV curves
dc.subjectcrystal structure
dc.subject4-aminobenzonitrile
dc.subjectMEP
dc.titleSynthesis, Crystal Structure and Cyclic Voltammetric Behavior of N-aroyl-N?-(4?-cyanophenyl)thioureas
dc.typeArticle

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