Palladium(II) Complexes Containing 2,6-Bis(Imino)Pyridines: Synthesis, Characterization, Thermal Study, and Catalytic Activity in Suzuki Reactions

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dc.authoridDayan, Osman / 0000-0002-0764-1965
dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.authoridDoğan, Fatih / 0000-0002-3088-886X
dc.authoridDoğan, Fatih / 0000-0001-5844-8893
dc.contributor.authorDayan, Osman
dc.contributor.authorDoğan, Fatih
dc.contributor.authorKaya, İsmet
dc.contributor.authorÇetinkaya, Bekir
dc.date.accessioned2025-01-27T20:24:20Z
dc.date.available2025-01-27T20:24:20Z
dc.date.issued2010
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractA series of palladium complexes: [(Pydim)PdCl](PdCl3) (Pydim (1): pyridine-2,6-diimine) have been synthesized from palladium dichloride and the corresponding pydim. The Pd (II) complexes have been used as catalyst in the Suzuki reaction of aryl halides. Moreover, thermal behaviors of palladium complexes have been studied in nitrogen atmosphere using TG/DTG and DTA techniques. The values of activation energy Ea, and reaction order n, the entropy change S*, enthalpy change H#, and Gibbs free energy change G# of the thermal decomposition were calculated by means of several methods based on the single heating rate.
dc.description.sponsorshipScientific and Technical Research Council of Turkey (TUBITAK) [107T808]; Canakkale Onsekiz Mart University Scientific Research Projects Commission [2009-16]
dc.description.sponsorshipThis research has been supported by The Scientific and Technical Research Council of Turkey (TUBITAK) (Project No: 107T808) and Canakkale Onsekiz Mart University Scientific Research Projects Commission (Project No: 2009-16).
dc.identifier.doi10.1080/15533174.2010.486822
dc.identifier.endpage344
dc.identifier.issn1553-3174
dc.identifier.issn1553-3182
dc.identifier.issue5
dc.identifier.scopus2-s2.0-77953005671
dc.identifier.scopusqualityN/A
dc.identifier.startpage337
dc.identifier.urihttps://doi.org/10.1080/15533174.2010.486822
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22163
dc.identifier.volume40
dc.identifier.wosWOS:000278165300008
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Inc
dc.relation.ispartofSynthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectactivation energy
dc.subjectPd(II) complexes
dc.subjectpyridine-2
dc.subject6-diimines
dc.subjectSuzuki reaction
dc.subjectthermal behavior
dc.titlePalladium(II) Complexes Containing 2,6-Bis(Imino)Pyridines: Synthesis, Characterization, Thermal Study, and Catalytic Activity in Suzuki Reactions
dc.typeArticle

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