The effect of perfluoroalkyl and hydrocarbon liquid chain lengths on oleophobic behaviors of copolymer surfaces

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dc.authoridOZEN CANSOY, ELIF/0000-0003-2275-042X
dc.authoridCengiz, Ugur/0000-0002-0400-3351
dc.contributor.authorCansoy, C. Elif
dc.contributor.authorCengiz, Ugur
dc.date.accessioned2025-01-27T20:22:43Z
dc.date.available2025-01-27T20:22:43Z
dc.date.issued2014
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this work, the effect of wt.% of perfluoroalkyl content and also hydrocarbon chain length on oleophobic properties of perfluoroethyl alkyl methacrylate-methyl methacrylate (Zonyl-TM-MMA) copolymers was investigated. The wetting performance of p(Zonyl-TM-ran-MMA) copolymer films by hydrocarbon liquids was found to be strongly depended on perfluoroalkyl chain lengths. Besides, increase in hydrocarbon chain length also caused an increase in contact angle results of p(Zonyl-TM-ran-MMA) copolymer films due to the stronger cohesion interactions of liquid molecules and this resulted in weaker adhesion interactions between copolymer surface and hydrocarbon drop. It was also discovered that contact angle hysteresis, Delta cos theta, values of copolymers depend on both wt.% Zonyl-TM content and also hydrocarbon chain length of liquids. (C) 2013 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.colsurfa.2013.10.039
dc.identifier.endpage700
dc.identifier.issn0927-7757
dc.identifier.issn1873-4359
dc.identifier.scopus2-s2.0-84887536633
dc.identifier.scopusqualityQ1
dc.identifier.startpage695
dc.identifier.urihttps://doi.org/10.1016/j.colsurfa.2013.10.039
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22008
dc.identifier.volume441
dc.identifier.wosWOS:000329260800089
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Bv
dc.relation.ispartofColloids and Surfaces A-Physicochemical and Engineering Aspects
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectOleophobic
dc.subjectPerfluoroalkyl chain length
dc.subjectHydrocarbon chain length
dc.subjectContact angle
dc.titleThe effect of perfluoroalkyl and hydrocarbon liquid chain lengths on oleophobic behaviors of copolymer surfaces
dc.typeArticle

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