Synthesis and characterization of novel urea and thiourea substitute cyclotriphosphazene compounds as naked-eye sensors for F- and CN- anions

[ X ]

Tarih

2015

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Tubitak Scientific & Technological Research Council Turkey

Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

Novel hexakisurea and thiourea cyclotriphosphazene compounds (3-7) were synthesized. The structure of all compounds was identified using FT-IR H-1, C-13, and P-31 NMR spectroscopy; MALDI-TOF MS; and elemental analysis. The optical sensor properties for anions of 3-7 were investigated using UV-Vis spectroscopy. It was determined that compounds 6 and 7 are spectrophotometric and naked eye sensors for F- and CN- anions, respectively. Sensor properties of these compounds for anions were investigated using UV-Vis spectroscopy. The stoichiometry of host guest complexes was found to be 1:6.

Açıklama

Anahtar Kelimeler

Cyclotriphosphazene, urea, thiourea, naked-eye sensor

Kaynak

Turkish Journal of Chemistry

WoS Q Değeri

Q3

Scopus Q Değeri

Q3

Cilt

39

Sayı

4

Künye