Synthesis and characterization of novel urea and thiourea substitute cyclotriphosphazene compounds as naked-eye sensors for F- and CN- anions
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Tarih
2015
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Tubitak Scientific & Technological Research Council Turkey
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Novel hexakisurea and thiourea cyclotriphosphazene compounds (3-7) were synthesized. The structure of all compounds was identified using FT-IR H-1, C-13, and P-31 NMR spectroscopy; MALDI-TOF MS; and elemental analysis. The optical sensor properties for anions of 3-7 were investigated using UV-Vis spectroscopy. It was determined that compounds 6 and 7 are spectrophotometric and naked eye sensors for F- and CN- anions, respectively. Sensor properties of these compounds for anions were investigated using UV-Vis spectroscopy. The stoichiometry of host guest complexes was found to be 1:6.
Açıklama
Anahtar Kelimeler
Cyclotriphosphazene, urea, thiourea, naked-eye sensor
Kaynak
Turkish Journal of Chemistry
WoS Q Değeri
Q3
Scopus Q Değeri
Q3
Cilt
39
Sayı
4