Determinetion of the thermodynamic properties of poly [ 2-(3-phenyl-3-methylcyclobutyl)-2-hydroxyethyl methacrylate-co-methacrylic acid ] at infinite dilution by inverse gas chromatography

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dc.contributor.authorKaya, İsmet
dc.contributor.authorDemirelli, Kadir
dc.date.accessioned2025-01-27T19:45:25Z
dc.date.available2025-01-27T19:45:25Z
dc.date.issued2001
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractSome thermodynamic quantities were obtained for the interactions of poly [2-(3-phenyl -3- methylcyclobutyl)-2-hydroxyethyl methacrylate-co-methacrylic acid] Poly (PCHEMA-co-MA) with alcohols, ketones, acetates, aromatics and n-alkanes by inverse gas chromatography in the temperature range of 150-180oC. The specific retention volumes, Vgo, weight fraction activity coefficients of solute probes at infinite dilution, $\\Omega 1\\infty$ and Flory-Huggins thermodynamic interaction parameters, $\\chi 12\\infty$ between polymers and solvents were determined. The partial molar free energy, $Delta G1\\infty$ , the partial molar heat of mixing, $Delta H1\\infty$ , at infinite dilution and the solubility parameters of the polymer, $\\delta$2 , were calculated. The copolymer was characterized by 1 H-NMR, FT-IR and DSC analyses
dc.identifier.endpage18
dc.identifier.issn1300-0527
dc.identifier.issn1303-6130
dc.identifier.issue1
dc.identifier.startpage11
dc.identifier.trdizinid33394
dc.identifier.urihttps://search.trdizin.gov.tr/tr/yayin/detay/33394
dc.identifier.urihttps://hdl.handle.net/20.500.12428/18307
dc.identifier.volume25
dc.indekslendigikaynakTR-Dizin
dc.language.isoen
dc.relation.ispartofTurkish Journal of Chemistry
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_TRD_20250125
dc.subjectKimya
dc.subjectUygulamalı
dc.subjectKimya
dc.subjectOrganik
dc.subjectPolimer Bilimi
dc.titleDeterminetion of the thermodynamic properties of poly [ 2-(3-phenyl-3-methylcyclobutyl)-2-hydroxyethyl methacrylate-co-methacrylic acid ] at infinite dilution by inverse gas chromatography
dc.typeArticle

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