Furan halkası içeren aromatik azometin polimerlerinin sentezi, karakterizasyonu, termal kararlılığı ve iletkenlik özelliklerinin incelenmesi
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Tarih
2007
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Çanakkale Onsekiz Mart Üniversitesi
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
4-[(5-metil-2-furil)metilenamino]fenol ve 2-[(5-metil-2-furil)metilenamino] fenol'ün oksidatif polikondenzasyon şartları incelendi. Reaksiyonlarda oksidant olarak NaOCl kullanıldı. Elde edilen ürünlerin yapı ve özellikleri FT-IR, UV-Vis, 1H-NMR, 13C-NMR, SEC, DTA-TGA, elektrometre ve döngüsel voltametri (CV) ile karakterize edildi. Anahtar Kelimeler: Oksidatif polikondenzasyon; Poli-4-[(5-metil-2- furil)metilenamino]fenol; Poli-2-[(5-metil-2-furil)metilenamino]fenol; Termal analiz; iletkenlik ve band boşluğu
The oxidative polycondensation reaction conditions of 4-[(5-methyl-2- furhyl)methyleneimino]phenol and 2-[(5-methyl-2-furhyl)methyleneimino]phenol were examined. NaOCl was used as oxidants in reactions. Both the structures and properties of the products were characterized by FT-IR, UV-Vis, 1H-NMR, 13CNMR, SEC, DTA-TGA, electrometre and cylic voltametry (CV). Keywords: Oxidative polycondensation; poly-4-[(5-methyl-2-furhyl) methyleneimino]phenol; poly-2-[(5-methyl-2-furhyl)methyleneimino]phenol; Thermal analysis; Conductivity and band gap.
The oxidative polycondensation reaction conditions of 4-[(5-methyl-2- furhyl)methyleneimino]phenol and 2-[(5-methyl-2-furhyl)methyleneimino]phenol were examined. NaOCl was used as oxidants in reactions. Both the structures and properties of the products were characterized by FT-IR, UV-Vis, 1H-NMR, 13CNMR, SEC, DTA-TGA, electrometre and cylic voltametry (CV). Keywords: Oxidative polycondensation; poly-4-[(5-methyl-2-furhyl) methyleneimino]phenol; poly-2-[(5-methyl-2-furhyl)methyleneimino]phenol; Thermal analysis; Conductivity and band gap.
Açıklama
Fen Bilimleri Enstitüsü, Kimya Ana Bilim Dalı
Anahtar Kelimeler
Kimya, Chemistry
