Catalytic Use of Pd(II) Complex Bearing 2-(thiophen-2-yl)-1H-Benzimidazole Ligand for The Reduction / Degradation of Multiple Mixtures Containing 4-NP, RhB and MB Organic Pollutants

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dc.contributor.authorYavasoglu, Melek Tercan
dc.date.accessioned2025-01-27T19:37:09Z
dc.date.available2025-01-27T19:37:09Z
dc.date.issued2023
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this study, the catalytic use of [Pd(L1)2]Cl2 complex is aimed for the reduction / degradation reactions of organic pollutants in water sources which pose a threat to the environment. For this purpose, 2-(thiophen-2-yl)-1H-benzimidazole ligand (L1) and its Pd(II) complex (C1) were synthesized and characterized by FT-IR, 1H-NMR, 13C-NMR, ESI-MS spectroscopic techniques. The catalytic efficiency of the C1 complex on the reduction of 4-nitro phenol compound (4-NP) and the degradation of rhodamine B (RhB), methylene blue (MB) dyes was investigated in the presence of NaBH4 in aqueous medium. The catalytic performance was examined with single solutions of these substrates (4-NP and RhB, MB dyes) and at the end of 5 minutes, over 92% conversion was observed for all three substrates. In the catalytic trials with 4-NP + RhB + MB triple substrate mixture, 84, 94 and 93% conversion values were obtained, respectively, after 5 minutes. C1 complex catalyst is very effective in the simultaneous reduction / degradation of these toxic organic compounds from aqueous environments without any competition or selectivity.
dc.identifier.doi10.53433/yyufbed.1167004
dc.identifier.endpage284
dc.identifier.issn1300-5413
dc.identifier.issn2667-467X
dc.identifier.issue1
dc.identifier.startpage271
dc.identifier.trdizinid1167770
dc.identifier.urihttps://doi.org/10.53433/yyufbed.1167004
dc.identifier.urihttps://search.trdizin.gov.tr/tr/yayin/detay/1167770
dc.identifier.urihttps://hdl.handle.net/20.500.12428/17135
dc.identifier.volume28
dc.indekslendigikaynakTR-Dizin
dc.language.isoen
dc.relation.ispartofYüzüncü Yıl Üniversitesi Fen Bilimleri Enstitüsü Dergisi
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_TRD_20250125
dc.subjectKimya
dc.subjectAnalitik
dc.subjectKimya
dc.subjectUygulamalı
dc.subjectMikrobiyoloji
dc.subjectÇevre Bilimleri
dc.titleCatalytic Use of Pd(II) Complex Bearing 2-(thiophen-2-yl)-1H-Benzimidazole Ligand for The Reduction / Degradation of Multiple Mixtures Containing 4-NP, RhB and MB Organic Pollutants
dc.typeArticle

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