Synthesis, spectroscopic studies and structure of 2-[(Benzo[d]thiazol-2- ylamino)methyl]phenol

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dc.contributor.authorYıldız, Mustafa
dc.contributor.authorÖzay, Hava
dc.contributor.authorÜnver, Hüseyin
dc.contributor.authorİskeleli, Nazan Ocak
dc.contributor.authorMehmet Zengin, D.
dc.contributor.authorDurlu, Tahsin Nuri
dc.date.accessioned2025-01-27T18:53:15Z
dc.date.available2025-01-27T18:53:15Z
dc.date.issued2010
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractSchiff base (E)-2-[(benzo[d]thiazol-2-ylimino)methyl]phenol (1) has been synthesized from the reaction of 2-hydroxy-benzaldehyde with 2-aminobenzothiazole. The 2-[(benzo[d]thiazol-2-ylamino)methyl]phenol (2) was prepared reduction of the Schiff base 1 with sodium borohydride. The compounds 1 and 2 have been characterized by elemental analysis, FT-IR, 1 H-NMR, 13 C-NMR and UV-visible spectroscopic techniques. The structure of the compound 2 has also been examined crystallographically. The compound 2 crystallizes in the monoclinic space group P2/c. The unit cell parameters were found as a = 10.017(1), b = 11.725(1), c = 10.341(1) Å, V = 1208.1(1) Å 3 , D x = 1.409 g cm -3 and Z = 4. The crystal structure was solved by direct methods and refined by the full-matrix least squares method and found as R 1 = 0.0308 and wR 2 = 0.0818 for 2032 for the observed reflections [I > 2?(I)]. Graphical Abstract: Crystal and molecular structure of the compound 2-[(benzo[d]thiazol-2- ylamino)methyl]phenol have been studied in order to reveal the presence of either the enol-imine or keto-amine forms related with hydrogen bonding by using FT-IR, 1 H-NMR, 13 C-NMR, UV-visible spectroscopic and X-ray crystallographic techniques.[Figure not available: see fulltext.] © 2010 Springer Science+Business Media, LLC.
dc.identifier.doi10.1007/s10870-010-9761-3
dc.identifier.endpage913
dc.identifier.issn1074-1542
dc.identifier.issue11
dc.identifier.scopus2-s2.0-78650003573
dc.identifier.scopusqualityQ3
dc.identifier.startpage909
dc.identifier.urihttps://doi.org/10.1007/s10870-010-9761-3
dc.identifier.urihttps://hdl.handle.net/20.500.12428/12649
dc.identifier.volume40
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer New York LLC
dc.relation.ispartofJournal of Chemical Crystallography
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_Scopus_20250125
dc.subjectCrystal structure; FT-IR; NMR; Spectroscopic studies; UV-visible
dc.titleSynthesis, spectroscopic studies and structure of 2-[(Benzo[d]thiazol-2- ylamino)methyl]phenol
dc.typeArticle

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