Thermogravimetric study of ionic Pt(II) complexes containing bis(diphenylthiophosphinyl)methane

Basit Öğe Kaydı
dc.contributor.authorDo?an, F.
dc.contributor.authorIrişli, S.
dc.date.accessioned2025-01-27T19:05:51Z
dc.date.available2025-01-27T19:05:51Z
dc.date.issued2009
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe TG-DTG and DTA study of dipositive platinum(II) complexes of the general formula [Pt(L-L)(dppmS2)](ClO4)2, where dppmS2 = Ph2P(S)CH2P(S)Ph2 and L-L = dppm (Ph2PCH2PPh2), dppe (Ph 2PCH2CH2PPh2), and dppp (Ph 2PCH2CH2CH2PPh2), were studied by thermogravimetric analysis from ambient temperature to 1000°C in nitrogen atmosphere. The decomposition occurred in one stage for [Pt(L-L)dppmS2](ClO4)2, [Pt(L-L)dpppS 2](ClO4)2 and [Pt(L-L)dppmS2] (ClO4)2 complexes. The values of activation energy, E, frequency factor, A, reaction order, n, entropy change, ?S?, enthalpy change, ?H?, and Gibss free energy change, ?G?, of the thermal decomposition were calculated by means of Coats-Redfern method (CR), MacCallum-Tanner method (MC) and van Krevelen method (vK). The activation energy values obtained by CR, MC and vK methods were in good agreement with each other.
dc.identifier.endpage6
dc.identifier.issn0137-5083
dc.identifier.issue1
dc.identifier.scopus2-s2.0-60549093819
dc.identifier.scopusqualityN/A
dc.identifier.startpage001
dc.identifier.urihttps://hdl.handle.net/20.500.12428/14004
dc.identifier.volume83
dc.indekslendigikaynakScopus
dc.language.isoen
dc.relation.ispartofPolish Journal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_Scopus_20250125
dc.subjectActivation energy; Ionic Pt(II) complexes; Thermal behaviour
dc.titleThermogravimetric study of ionic Pt(II) complexes containing bis(diphenylthiophosphinyl)methane
dc.typeArticle

Dosyalar

Koleksiyon

Scopus İndeksli Yayınlar Koleksiyonu