Synthesis and characterization of metal ion-imprinted polymers

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dc.authorid(Caldiran) Isikver, Yasemin/0000-0001-6481-188X
dc.contributor.authorIsikver, Yasemin
dc.contributor.authorBaylav, Sabri
dc.date.accessioned2025-01-27T20:59:41Z
dc.date.available2025-01-27T20:59:41Z
dc.date.issued2018
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this study, ion-imprinted polymeric materials from an aqueous solution were prepared to remove metal ions (M2+) like Ni2+, Co2+, etc. To prepare ion-imprinted polymers (IIPs), acrylic acid derivatives (XA) like acrylamide (AAm), methacrylic acid and itaconic acid were chosen as monomers. Metal ions formed binary chelate complexes with the help of 8-hydroxyquinoline (8-HQ). The solution containing functional monomers and the binary complex were polymerizedwith the help of various cross-linkers [ethylene glycol dimethylacrylate (EGDMA) or trimethylpropane trimethacrylate (TMPTMA)] and the target ion was removed from this polymer through an applicable method to produce IIPs. Furthermore, the control polymers (CPs) were synthesized through the same method without using metal ion. Characterization of the polymeric materials was investigated through spectroscopic (FTIR/ATR), thermal (TGA, DSC) and surface (SEM and XRD) analyses. Functional monomers, cross-linkers and the target ion's species were changed during preparation of IIPs to observe their effect on imprinting of the target ion. Adsorption of the target ion to the prepared IIPs and the factors affecting the adsorption like concentration, pH, temperature, mass, etc. were studied.
dc.description.sponsorshipCumhuriyet University Scientific Research Unit [F-322]
dc.description.sponsorshipThis work was supported by the Cumhuriyet University Scientific Research Unit (Project No. F-322). We thank the Cumhuriyet University Scientific Research Unit.
dc.identifier.doi10.1007/s12034-018-1578-2
dc.identifier.issn0250-4707
dc.identifier.issn0973-7669
dc.identifier.issue2
dc.identifier.urihttps://doi.org/10.1007/s12034-018-1578-2
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26781
dc.identifier.volume41
dc.identifier.wosWOS:000430795900031
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.language.isoen
dc.publisherIndian Acad Sciences
dc.relation.ispartofBulletin of Materials Science
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WoS_20250125
dc.subjectIon-imprinted polymers
dc.subjectacrylamide
dc.subjectacrylic acid derivatives
dc.subjectheavy metal ions
dc.subject8-hydroxyquinoline
dc.titleSynthesis and characterization of metal ion-imprinted polymers
dc.typeArticle

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