Phenacyl methacrylate and N-vinyl-2-pyrrolidone copolymers: Synthesis, characterization, and reactivity ratios

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dc.authoridSoykan, Cengiz/0000-0002-5802-5097
dc.contributor.authorSoykan, C
dc.contributor.authorCoskun, M
dc.contributor.authorAhmedzade, M
dc.contributor.authorOzdemir, E
dc.date.accessioned2025-01-27T20:34:35Z
dc.date.available2025-01-27T20:34:35Z
dc.date.issued2000
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe free radical copolymerization of phenacyl methacrylate (PAMA) and N-Vinyl-2-pyrrolidone (N-Vp) was carried out using 2,2'-azobisisobutyronitrile (AIBN), in 1,4-dioxane solution at 70 degrees C. The polymers were characterized by FT-IR, H-1- and C-13-NMR spectroscopic methods. Solubility parameters, inherent viscosities, average molecular weight and densities of polymers were determined. Thermal properties of the homo- and copoly-mers were also studied by thermogravimetric analysis and differantial scanning calorimetry. The percentage composition of the copolymers were established by microelemental analysis. The copolymerization reactivity ratios were computed using the Fineman-Ross and Kelen-Tudos methods. The experimental data indicate random comonomer incorporation with a slightly alternating tendency.
dc.identifier.doi10.1081/MA-100101142
dc.identifier.endpage1101
dc.identifier.issn1060-1325
dc.identifier.issue9
dc.identifier.startpage1089
dc.identifier.urihttps://doi.org/10.1081/MA-100101142
dc.identifier.urihttps://hdl.handle.net/20.500.12428/23365
dc.identifier.volume37
dc.identifier.wosWOS:000089098800010
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.language.isoen
dc.publisherMarcel Dekker Inc
dc.relation.ispartofJournal of Macromolecular Science-Pure and Applied Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectphenacyl methacrylate
dc.subjectN-vinyl-2-pyrrolidone
dc.subjectcopolymers
dc.subjectcharacterization
dc.subjectreactivity ratios
dc.subjectelemental analysis
dc.subjectthermogravimetric analysis
dc.titlePhenacyl methacrylate and N-vinyl-2-pyrrolidone copolymers: Synthesis, characterization, and reactivity ratios
dc.typeArticle

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