A Kinetic Evaluation for PANSA Doped Low Density Polyethylene Blends

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dc.authoridDoğan, Fatih / 0000-0002-3088-886X
dc.authoridBilici, Ali / 0000-0002-1377-5580
dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.contributor.authorDoğan, Fatih
dc.contributor.authorBilici, Ali
dc.contributor.authorKaya, İsmet
dc.contributor.authorŞirin, Mehtap
dc.date.accessioned2025-01-27T19:22:41Z
dc.date.available2025-01-27T19:22:41Z
dc.date.issued2019
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn our previous study, we prepared blends of lowdensity polyethylene (LDPE) with semiconductorpolymer, poly (1-amino-2-hydroxynaphthalene-4-sulfonic acid) (PANSA), in different mixing ratios. Inthat study, the findings on some physical and chemical properties of the blends prepared were alsopresented. In this study, it was aimed to investigate the thermal decomposition kinetics of these preparedblends. For this purpose, thermograms of PANSA doped LDPE blends at four different heating rates wereobtained. With the addition of PANSA into LDPE, it was observed that the initial decompositiontemperature and maximum decomposition temperature of LDPE increased. Thermal decompositionkinetics of blends were performed using the integral isoconversional methods (Kissinger, Kim-Park (KP),Tang, Kissenger-Akahira-Sunose (KAS) and Flynn-Wall-Ozawa (FWO)) in addition to differentialisoconversional method (Friedman method). The activation energy values calculated by Kissinger, KP,Tang, KAS, FWO and Friedman methods and found to be 187.9, 200.2, 171.90, 171.78, 171.70 and171.89 kJ mol-1for 0.5 % PANSA doped LDPE, 193.9, 206.2, 173.31, 172.87, 172.98 and 172.78 kJmol-1for 1 % PANSA doped LDPE and 207.0, 219.2, 196.94, 197.09, 198.08 and 208.10 kJ mol-1for 0.5% PANSA doped LDPE, respectively. Thermal decomposition mechanism for blends was proposed withthe help of master plot curves.
dc.identifier.doi10.18466/cbayarfbe.635079
dc.identifier.endpage349
dc.identifier.issn1305-130X
dc.identifier.issn1305-1385
dc.identifier.issue4
dc.identifier.startpage343
dc.identifier.trdizinid383777
dc.identifier.urihttps://doi.org/10.18466/cbayarfbe.635079
dc.identifier.urihttps://search.trdizin.gov.tr/tr/yayin/detay/383777
dc.identifier.urihttps://hdl.handle.net/20.500.12428/15181
dc.identifier.volume15
dc.indekslendigikaynakTR-Dizin
dc.language.isoen
dc.relation.ispartofCelal Bayar Üniversitesi Fen Bilimleri Dergisi
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_TRD_20250125
dc.subjectPolimer Bilimi
dc.subjectMühendislik
dc.subjectKimya
dc.titleA Kinetic Evaluation for PANSA Doped Low Density Polyethylene Blends
dc.typeArticle

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