Synthesis and structural X-ray analysis of 1,1’-(naphthalene-1,8-diyl)-3,3’-dibenzoyl-bisthiourea and its use as anion-binding receptor

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dc.contributor.authorAydın, Fatma
dc.contributor.authorTunoğlu, Nazan
dc.contributor.authorAykaç, Doğan
dc.contributor.authorArslan, Nahide Burcu
dc.contributor.authorKazak, Canan
dc.date.accessioned2025-01-27T20:01:15Z
dc.date.available2025-01-27T20:01:15Z
dc.date.issued2012
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractA novel artificial receptor, 1,1’-(naphthalene-1,8-diyl)-3,3’-dibenzoyl-bisthiourea, based on a 1,8-naphthalene skeleton bearing bisthiourea groups was prepared and characterized by IR and $^1H-NMR, ^13C-NMR$, and MS spectroscopic techniques. The compound proved to be an efficient and selective naked-eye detector for the fluoride, cyanide, and hydroxide ions in DMSO. The crystal structure of the title compound was examined by using X-ray crystallographic techniques and found to be crystallized in the monoclinic space group P − 1 with the unit cell parameters: a = 8.1556(8) $\\AA$, b = 12.0127(11) $\\AA$, c = 13.2081(11) $\\AA$, α = 109.510(7) ◦ , β = 95.390(7)◦, γ = 103.660(7)◦ , Z = 2. The intramolecular N-H· · ·O hydrogen bondinginteractions between the N-H and the oxygen atom of C=O groups support a 1,1’-(naphthalene-1,8-diyl)- 3,3’-dibenzoyl-bisthiourea framework. Moreover, the combinations of N—H· · ·S bonds produce $R^2_2$ (8)rings.
dc.identifier.endpage777
dc.identifier.issn1300-0527
dc.identifier.issn1303-6130
dc.identifier.issue5
dc.identifier.startpage764
dc.identifier.trdizinid138584
dc.identifier.urihttps://search.trdizin.gov.tr/tr/yayin/detay/138584
dc.identifier.urihttps://hdl.handle.net/20.500.12428/20024
dc.identifier.volume36
dc.indekslendigikaynakTR-Dizin
dc.language.isoen
dc.relation.ispartofTurkish Journal of Chemistry
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_TRD_20250125
dc.subjectKimya
dc.subjectOrganik
dc.titleSynthesis and structural X-ray analysis of 1,1’-(naphthalene-1,8-diyl)-3,3’-dibenzoyl-bisthiourea and its use as anion-binding receptor
dc.typeArticle

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