Addition of dibromocarbene to cyclobutene: Characterisation and mechanism of formation of the products
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Tarih
2004
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Scientific Reviews Ltd.
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Cyclobutene reacted with dibromocarbene in solution to give 1,5-dibromocyclopent-1-ene (9), 1,2,6, 6-tetrabromobicyclo[3.1.0]hexane (10), and 1,2,3,6-tetrabromocyclohex-1-ene (11), in a ratio of 1:4:8, respectively. Compounds 10 and 11 were found to be formed from a second carbene addition and rearrangement under the given reaction conditions.
Açıklama
Anahtar Kelimeler
Carbene; Carbene addition; Cyclobutene; Cyclopropane
Kaynak
Journal of Chemical Research
WoS Q Değeri
Scopus Q Değeri
Q3
Cilt
Sayı
10
