Synthesis and characterization of fluorescent graft fluorene-co-polyphenol derivatives: The effect of substituent on solubility, thermal stability, conductivity, optical and electrochemical properties

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dc.authoridKaya, Ismet/0000-0002-9813-2962
dc.contributor.authorKaya, İsmet
dc.contributor.authorYıldırım, Mehmet
dc.contributor.authorAydın, Aysel
dc.contributor.authorSenol, Dilek
dc.date.accessioned2025-01-27T20:41:48Z
dc.date.available2025-01-27T20:41:48Z
dc.date.issued2010
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractA series of fluorene Schiff bases and their oligophenol derivatives were successfully synthesized using the condensation and graft copolymerization reactions, respectively. The synthesized compounds were good soluble in common organic solvents. Photoluminescence (PL) properties of the synthesized materials were determined in solution forms. As to the fluorene copolymers (FPs), higher PL intensities were obtained when compared with the monomeric models. Solvent effects on the fluorescence spectra and possible usages in spectrofluorometric ion sensors of the FPs were discussed. Optical and electrochemical band gaps of the polymers were lower than those of the Schiff bases indicating the more conjugated structures of the FPs. The oxidized states of the novel fluorene compounds were also examined by cyclic voltammetry (CV) technique. The solid state conductivity measurements showed that the synthesized FPs were semiconductors and when exposed to the iodine vapour their conductivities could be increased up to four orders of magnitude. The polymer having the lower band gap (FP-3) had also the highest undoped conductivity. Thermal characterizations of the synthesized compounds were carried out by TG-DTA and DSC methods. The initial degradation temperatures of the FPs were found quite high in the range of 220-300 degrees C. (C) 2010 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipTUBITAK Grants Commission [TBAG-107T414]
dc.description.sponsorshipThe authors thank TUBITAK Grants Commission for a research grant (Project No: TBAG-107T414).
dc.identifier.doi10.1016/j.reactfunctpolym.2010.07.013
dc.identifier.endpage826
dc.identifier.issn1381-5148
dc.identifier.issn1873-166X
dc.identifier.issue10
dc.identifier.startpage815
dc.identifier.urihttps://doi.org/10.1016/j.reactfunctpolym.2010.07.013
dc.identifier.urihttps://hdl.handle.net/20.500.12428/24242
dc.identifier.volume70
dc.identifier.wosWOS:000282460700015
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofReactive & Functional Polymers
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectGraft copolymer
dc.subjectOligophenol
dc.subjectFluorescence
dc.subjectConjugated polymers
dc.subjectPolyfluorene
dc.titleSynthesis and characterization of fluorescent graft fluorene-co-polyphenol derivatives: The effect of substituent on solubility, thermal stability, conductivity, optical and electrochemical properties
dc.typeArticle

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