1,3-dioksasikloalkan alkilamino grupları içeren ligandların metal komplekslerinin sentezi ve karakterizasyonu
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Date
2001
Authors
Journal Title
Journal ISSN
Volume Title
Publisher
Çanakkale Onsekiz Mart Üniversitesi
Access Rights
info:eu-repo/semantics/closedAccess
Abstract
OZ: Bu çalışmada, 6,7-0-siklohekziliden-l-amino-4-azaheptan (Lı) ve 5,6-0-siklohekziliden-l-amino-3-azahekzan (L2) ligandlan iki basamakta sentezlenmiştir. Daha sonra bu ligandlar ile çeşitli metallerin kompleksleri elde edilmiştir. Elde edilen ligandlar birinci basamakta epiklorhidrin, siklohekzanon ile reaksiyona sokularak l-klor-2,3-0-siklohekziliden propan (1) hazırlanmıştır. Çalışmanın ikinci basamağında (1) bileşiğinin 1,3-diaminopropan ile reaksiyonu sonucunda (Lı) elde edilmiştir ve (1) bileşiğinin 1,2-diaminoetan ile reaksiyonu sonucunda (L2) elde edilmiştir. Çalışmanın üçüncü basamağında, (Lı) ve (L2) ligandlan ile Cu(ll), Ni(II) ve Co(II) kompleksleri hazırlandı. Bu komplekslerin yapılan ve özellikleri elementel analiz, İR, NMR, UV ve manyetik süsseptibilite yardımıyla aydınlatıldı. Anahtar Kelimeler: Aza, Amino, Kompleks, Diaminoalkil, Siklohekziliden, 1,3-Dioksa, Siklohekzanon, Geçiş metalleri.
ABSTRACT: In this work, 6,7-0-cyclohexilidine-l-amino-4-azaheptane (Li) and 5,6-0-cyclohexilydine-l-amino-3azahexane (L2) ligands were synthesized in two steps. Then, various metal complexes were obtained with these ligands. At the first step, l-chloro-2,3-0-cyclohexlidine propane (1) was prepared by means of the reaction of the obtained ligands with the epichlorhydrine and cyclohexanone. At the second step, (Li) was obtained from the reaction of (1) with 1,3-diaminopropane and (L2) was obtained from the reaction of (1) with 1,2-diaminethane. At the third step, the complexes of Cu(II), Ni(II) and Co(II) with ligands (Li) and (L2) were prepared. The structures and properties of these complexes were investigeted by means of elementel analysis, IR, UV, NMR spectroscopy and magnetic sussceptibility measurmeuts. Key Words: Aza, Amino, Complex, Diaminoalkyl, Cyclohexilydine, 1,3-Dioxa, Cyclohexanon, Transation metals. II
ABSTRACT: In this work, 6,7-0-cyclohexilidine-l-amino-4-azaheptane (Li) and 5,6-0-cyclohexilydine-l-amino-3azahexane (L2) ligands were synthesized in two steps. Then, various metal complexes were obtained with these ligands. At the first step, l-chloro-2,3-0-cyclohexlidine propane (1) was prepared by means of the reaction of the obtained ligands with the epichlorhydrine and cyclohexanone. At the second step, (Li) was obtained from the reaction of (1) with 1,3-diaminopropane and (L2) was obtained from the reaction of (1) with 1,2-diaminethane. At the third step, the complexes of Cu(II), Ni(II) and Co(II) with ligands (Li) and (L2) were prepared. The structures and properties of these complexes were investigeted by means of elementel analysis, IR, UV, NMR spectroscopy and magnetic sussceptibility measurmeuts. Key Words: Aza, Amino, Complex, Diaminoalkyl, Cyclohexilydine, 1,3-Dioxa, Cyclohexanon, Transation metals. II
Description
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Fen Bilimleri Enstitüsü, Kimya Ana Bilim Dalı
Fen Bilimleri Enstitüsü, Kimya Ana Bilim Dalı
Keywords
Kimya, Chemistry
