Application of a cyclic renewable silver amalgam liquid film electrode (R-AgLAFE) to study the electroreduction processes of Bi(III) ions in the presence of cysteine
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Tarih
2022
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
The cyclically refreshable liquid silver amalgam film silver-based electrode (R-AgLAFE) to study electrode processes under the “cap-pair” conditions were used. The effects of cysteine on the kinetics and the mechanism of Bi(III) electroreduction in chlorates(VII) have been studied. The methodology of the study is based on electrochemical methods: DC polarography, square wave voltammetric (SWV), and cyclic voltammetric (CV). The magnitude of the catalytic effect is related to the formation of the $Bi(III)-Hg(SR)_2$ active complexes mediating electron transfer equilibrium. This reaction controls the total rate of the process.
Açıklama
Anahtar Kelimeler
Kimya, Uygulamalı
Kaynak
Turkish Journal of Analytical Chemistry (Online)
WoS Q Değeri
Scopus Q Değeri
Cilt
4
Sayı
1
