Solid State Decomposition Kinetics of Green Light Emitting Polyphenol Nanoparticles

dc.authoridDoğan, Fatih / 0000-0002-3088-886X
dc.authoridDoğan, Fatih / 0000-0001-5844-8893
dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.contributor.authorDoğan, Fatih
dc.contributor.authorKaya, İsmet
dc.date.accessioned2025-01-27T20:47:34Z
dc.date.available2025-01-27T20:47:34Z
dc.date.issued2016
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe reaction process and kinetic parameters related to the solid state decomposition of green light emitting polyphenol nanoparticles (GLPN) synthesized by oxidative polymerization were investigated by thermogravimetric analysis technique (TG) at different heating rates. TG/DTG-DTA curves showed that the thermal decomposition occurred mainly in one stages. The kinetic parameters related to solid state decomposition stage of GLPN were calculated by using the methods based on multiple heating rates such as Kissinger, Kim-Park (KM), Tang, Flynn-Wall-Ozawa (FWO), Friedman (FR) and Kissinger-Akahira-Sunose (KAS). The activation energies obtained by Kissinger, Kim-Park, Tang, KAS, FWO, and FR methods were found to be 157.5, 158.0, 166.9, 165.8, 167.1 kJ/mol, respectively, in a wide range of conversion. Furthermore the reaction process related to the solid state decomposition stage of GLPN was also determined by using integral procedure Coats-Redfern (CR) and master plots. The analysis of the so-called methods showed that the solid state decomposition mechanism of polyphenol derivatives nanoparticles in N-2 went to the D-n mechanism (dimensional diffusion, n = 6).
dc.identifier.doi10.1166/mat.2016.1297
dc.identifier.endpage10
dc.identifier.issn2169-429X
dc.identifier.issn2169-4303
dc.identifier.issue1
dc.identifier.startpage5
dc.identifier.urihttps://doi.org/10.1166/mat.2016.1297
dc.identifier.urihttps://hdl.handle.net/20.500.12428/24966
dc.identifier.volume5
dc.identifier.wosWOS:000374021600002
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.language.isoen
dc.publisherAmer Scientific Publishers
dc.relation.ispartofMaterials Focus
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WoS_20250125
dc.subjectGreen Light Emitting Polyphenol Nanoparticles (GLPN)
dc.subjectThermogravimetric Analysis
dc.subjectActivation Energy
dc.subjectDecomposition Mechanism
dc.titleSolid State Decomposition Kinetics of Green Light Emitting Polyphenol Nanoparticles
dc.typeReview Article

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