Newly Soluble and Non-Aggregated Copper(II) and Tin(II) Phthalocyanines: Synthesis, Characterization and Investigation of Photophysical and Photochemical-Responsive

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dc.contributor.authorPişkin, Mehmet
dc.contributor.authorÖztürk, Ömer Faruk
dc.contributor.authorOdabaş, Zafer
dc.date.accessioned2025-01-27T19:38:50Z
dc.date.available2025-01-27T19:38:50Z
dc.date.issued2017
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThis work presents the synthesis and characterization of non-aggregated and highly soluble copper(II) and tin(II) phthalocyaninessubstituted with 2,6-dimethoxyphenoxy groups at the non-peripheral (alpha) and peripheral (beta) positions. The phthalocyanines havebeen characterized by common spectroscopic techniques. They show excellent solubility and non-aggregated species in common organicsolvents such as dimethylsulfoxide, dimethylformamide, tetrahydrofuran, toluene, acetonitrile, chloroform and dichloromethane, whichmake them candidates to use for many applications in different fields of science and technology. The effects positions of substituenton the phthalocyanine skeleton and the variety of central metal ions on the phthalocyanine of aggregation and on their spectroscopicproperties were determined in different solvents as mentioned above. The novel synthesized copper phthalocyanines were not evaluatedfor fluorescence, photophysical and photochemical properties due to transition metal and paramagnetic behavior of central metalin the phthalocyanine cavity. The effects of substituent and their positions on the tin(II) phthalocyanines’ on their photophysical(fluorescence quantum yields and lifetimes) and photochemical properties (singlet oxygen generation and photodegradation underlight irradiation) were also investigated and reported in dimethylsulfoxide for the first time.
dc.identifier.doi10.7212/zkufbd.v7i2.356
dc.identifier.endpage637
dc.identifier.issn2146-4987
dc.identifier.issn2146-7277
dc.identifier.issue2
dc.identifier.startpage627
dc.identifier.trdizinid294422
dc.identifier.urihttps://doi.org/10.7212/zkufbd.v7i2.356
dc.identifier.urihttps://search.trdizin.gov.tr/tr/yayin/detay/294422
dc.identifier.urihttps://hdl.handle.net/20.500.12428/17389
dc.identifier.volume7
dc.indekslendigikaynakTR-Dizin
dc.language.isoen
dc.relation.ispartofKaraelmas Fen ve Mühendislik Dergisi
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_TRD_20250125
dc.subjectKimya
dc.subjectUygulamalı
dc.subjectKimya
dc.subjectOrganik
dc.subjectMühendislik
dc.subjectKimya
dc.titleNewly Soluble and Non-Aggregated Copper(II) and Tin(II) Phthalocyanines: Synthesis, Characterization and Investigation of Photophysical and Photochemical-Responsive
dc.typeArticle

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