Dopant Free Donor-Acceptor Type Polymer Hole Transport Materials for Efficient and Stable Perovskite Solar Cells

Basit Öğe Kaydı
dc.authoridgultekin, burak/0000-0002-8804-7844
dc.authoridKARAMAN, MERVE/0000-0003-2803-7414
dc.authoridKoyuncu, Sermet/0000-0001-8352-8326
dc.contributor.authorAkin Kara, Duygu
dc.contributor.authorTurgut, Sevdiye Basak
dc.contributor.authorCirak, Dilek
dc.contributor.authorKaraman, Merve
dc.contributor.authorCan, Mustafa
dc.contributor.authorKoyuncu, Sermet
dc.contributor.authorGultekin, Burak
dc.date.accessioned2025-01-27T20:35:16Z
dc.date.available2025-01-27T20:35:16Z
dc.date.issued2024
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractA new donor-acceptor type polymers containing benzothiadiazole (HB1) and benzoselenidiazole (HB2) as acceptor units were prepared or use as hole transport layers in perovskite solar cells (PSCs). It was observed that the electrochemical HOMO-LUMO band gap narrowed from 2.74 to 1.88 depending on the variation in the acceptor unit. In addition, the charge-transfer band at 580 nm undergoes a 30 nm red-shift and broadens to the near-infrared region. HB1 and HB2 were introduced as dopant-free HTMs to replace the commonly used 2,2 ',7,7 '-tetrakis[N,N-di(4-methoxyphenyl)amino]-9-9 '-spirobifluorene (spiro-OMeTAD) in planar heterojunction n-i-p type of PSCs. Compared with HB2, HB1 exhibited better film morphology and mobility, resulting in improved charge-carrier extraction and transport. Dopant-free HB1 devices fabricated using the Cs0.05FA0.79MA0.16-Pb (IxBr1-x)3 triple cation perovskite displayed a champion power conversion efficiency of 11.69% under one sun illumination (100 mW cm(-2)) which is higher than the efficiency of HB2-based devices. The inflated performance was attributed to the reduced charge recombination and improved conductivity. In addition, these new HTMs exhibited higher hydrophobicity and thermal stability than their doped spiro-OMeTAD counterpart, making it possible to achieve good stability.
dc.description.sponsorshipTUBITAK1003-Primary SubjectsR and D Funding Program [218M940]
dc.description.sponsorshipTUBITAK1003-Primary SubjectsR and D Funding Program (Project No: 218M940)
dc.identifier.doi10.1021/acsaenm.3c00818
dc.identifier.endpage2015
dc.identifier.issn2771-9545
dc.identifier.issue8
dc.identifier.startpage2007
dc.identifier.urihttps://doi.org/10.1021/acsaenm.3c00818
dc.identifier.urihttps://hdl.handle.net/20.500.12428/23615
dc.identifier.volume2
dc.identifier.wosWOS:001273639400001
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.language.isoen
dc.publisherAmer Chemical Soc
dc.relation.ispartofAcs Applied Engineering Materials
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectpolymer
dc.subjecthole transport layer
dc.subjectperovskite solarcell
dc.subjectdopant-free
dc.subjectDFT calculation
dc.titleDopant Free Donor-Acceptor Type Polymer Hole Transport Materials for Efficient and Stable Perovskite Solar Cells
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu