Synthesis, characterization and thermal degradation of oligo-2-[(4- iodophenylimino)methyl|phenol and ol1gomer-metal complexes

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dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.contributor.authorKaya, İsmet
dc.contributor.authorMoral, Fatma
dc.contributor.authorÖzdemir, Eyüp
dc.date.accessioned2025-01-27T19:02:56Z
dc.date.available2025-01-27T19:02:56Z
dc.date.issued2009
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe conditions for oxidative condensation of 2-[(4-iodophenylimino)methyl] pheno| (1P1MP) were studied with air and NaOCI as oxidants in an aqueous alkaline medium between 50 and 90°C. Size exclusion chromatography (SEC) showed that the number-average molecular weight (Mn), weight-average molecular weight (Mw) and polydispersity index (PDI) values, respectively, were 1250, 1300 g mol-1 and 1.040 for oxidation with NaOCI and 2200, 2500 g mol-1 and 1.136 for oxidation by air. With the optimum reaction conditions, the yield of OIPIMP was found to be 67 % with NaOCI, and 29 % with air, as oxidant. The OIPIMP was characterized by 1H-NMR, 13C-NMR, FT-1R, UV-Vis and elemental analysis. Metal complexes of the oligomerwere shown to be more thermally stable than OIPIMP itself. © 2009 Chemical Society of Ethiopia.
dc.identifier.endpage62
dc.identifier.issn1011-3924
dc.identifier.issue1
dc.identifier.scopus2-s2.0-66849121906
dc.identifier.scopusqualityQ3
dc.identifier.startpage55
dc.identifier.urihttps://hdl.handle.net/20.500.12428/13724
dc.identifier.volume23
dc.indekslendigikaynakScopus
dc.language.isoen
dc.relation.ispartofBulletin of the Chemical Society of Ethiopia
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_Scopus_20250125
dc.subjectOligo-2-[(4-iodophenylimino)methyl]phenol; Oligomer-metal complexes; Oxidative polycondensation; Thermal analysis
dc.titleSynthesis, characterization and thermal degradation of oligo-2-[(4- iodophenylimino)methyl|phenol and ol1gomer-metal complexes
dc.typeArticle

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