Syntheses, Spectroscopic, and Thermal Characterization of Cu(II), Ni(II), and Pt(II) Complexes of Some Tridentate Ligands

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dc.authoridKarabulut, H.R. Ferhat/0000-0002-9501-6296
dc.contributor.authorTurkyilmaz, Murat
dc.contributor.authorKarabulut, Ferhat
dc.contributor.authorAltun, Ozlen
dc.contributor.authorBaran, Yakup
dc.date.accessioned2025-01-27T20:14:41Z
dc.date.available2025-01-27T20:14:41Z
dc.date.issued2013
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe study emphasized azomethine coordination compounds of Pt(II), Cu(II), and Ni(II) having tetracoordinate geometry around the metal ions with the general formula, [MLCl]Cl, where L, azomethine have been isolated in the solid state. All the ligands were identified by spectroscopic methods and elemental analysis. The synthesized coordination compounds have been characterized by FTIR, magnetic measurements, elemental analysis, electrical conductance, and thermal analysis. Square planar structures have been proposed for the Ni(II) and Pt(II) complexes. Magnetic susceptibility measurements and electronic spectra of the complexes sustain the proposed square planer structures. The complexes thermally stable and this thermal stability is discussed in terms of ligands donor atoms, geometry and central metal ions. Azomethine complexes have a similar thermal behavior for the selected metal ions. The TG analyses suggest high thermal stability for most complexes followed by thermal decomposition in different steps. The decomposition processes were observed as water elimination, chloride anion removal, and degradation of the organic ligands. Supplemental materials are available for this article. Go to the publisher's online edition of Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry to view the supplemental file.
dc.description.sponsorshipTrakya University TBAP [2011-113]
dc.description.sponsorshipThe authors thank the Trakya University TBAP 2011-113 for the financial support.
dc.identifier.doi10.1080/15533174.2012.757746
dc.identifier.endpage1273
dc.identifier.issn1553-3174
dc.identifier.issue9
dc.identifier.startpage1267
dc.identifier.urihttps://doi.org/10.1080/15533174.2012.757746
dc.identifier.urihttps://hdl.handle.net/20.500.12428/21172
dc.identifier.volume43
dc.identifier.wosWOS:000321888400008
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.language.isoen
dc.publisherTaylor & Francis Inc
dc.relation.ispartofSynthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectazomethine
dc.subjectcomplexes
dc.subjectmetal ions
dc.subjectTG-DTA
dc.subjectthermal stability
dc.subjecttridentate
dc.titleSyntheses, Spectroscopic, and Thermal Characterization of Cu(II), Ni(II), and Pt(II) Complexes of Some Tridentate Ligands
dc.typeArticle

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