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    Intramolecular excimer formation in hexakis(pyrenyloxy)cyclotriphosphazene: photophysical properties, crystal structure, and theoretical investigation
    (Royal Soc Chemistry, 2014) Yesilot, Serkan; Cosut, Bunyemin; Alidagi, Husnuye Ardic; Hacivelioglu, Ferda; Ozpinar, Gul Altinbas; Kilic, Adem
    A hexakis(pyrenyloxy) cyclotriphosphazene is synthesized by the reaction of N3P3Cl6 with 2-hydroxypyrene, and its excimer emission through intramolecular interactions in solution and in the solid state has been investigated by fluorescence spectroscopy and X-ray crystallography. Thermal and electrochemical properties were investigated. A DFT benchmark study has been performed to evaluate the intramolecular interactions and molecular orbital levels by comparing with the experimental results.