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Öğe Comparison effects and electron spin resonance studies of ?-Fe2O4 spinel type ferrite nanoparticles(Pergamon-Elsevier Science Ltd, 2014) Bayrakdar, H.; Yalcin, O.; Cengiz, U.; Ozum, S.; Anigi, E.; Topel, O.alpha-Fe2O4 spinel type ferrite nanoparticles have been synthesized by cetyltrimethylammonium bromide (CTAB) and ethylenediaminetetraacetic acid (EDTA) assisted hydrothermal route by using NaOH solution. Electron spin resonance (ESR/EPR) measurements of alpha-Fe2O4 nanoparticles have been performed by a conventional x-band spectrometer at room temperature. The comparison effect of nanoparticles prepared by using CTAB and EDTA in different alpha-doping on the structural and morphological properties have been investigated in detail. The effect of EDTA-assisted synthesis for alpha-Fe2O4 nanoparticles are refined, and thus the spectroscopic g-factor are detected by using ESR signals. These samples can be considered as great benefits for magnetic recording media, electromagnetic and drug delivery applications. (C) 2014 Elsevier B.V. All rights reserved.Öğe Martensitic and austenitic transformations in core-surface cubic nanoparticles(Elsevier Science Bv, 2015) Ozum, S.; Yalcin, O.; Erdem, R.; Bayrakdar, H.; Eker, H. N.As a continuation of our recently published work, we have used the pair approximation in Kikuchi version to investigate martensitic and austenitic transformations in homogeneous (HM) and composite (CM) cubic nanoparticles (CNPs) based on the Blume-Emery-Griffiths model. A single cubic nanoparticle made of a core surrounded by a surface is considered as shaped in two dimensional (2D) square arrays instead of hexagonal array. From the phase diagrams of HM and CM-CNPs it has been observed that the martensitic-austenitic transformations (MT-AT) occurred. The influence of the exchange coupling and single-ion anisotropy parameters in the model Hamiltonian on the MT-AT is studied and analyzed in comparison with the results for hexagonal nanoparticles. Significant changes of the phase transition points and hysteresis behaviours depending upon the particle structure have been discussed. (C) 2014 Elsevier B.V. All rights reserved.











